4.7 Article

Elucidating the charge storage mechanism of carbonaceous and organic electrode materials for sodium ion batteries

Journal

CHEMICAL COMMUNICATIONS
Volume 57, Issue 99, Pages 13465-13494

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/d1cc04925a

Keywords

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Funding

  1. First Research in Lifetime grant from the National Research Foundation of Korea (NRF) [NRF-2018R1C1B5047313]
  2. National Research Foundation of Korea (NRF) [NRF-2017M3D1A1039561, NRF-2017R1A5A1015365, NRF-2017R1A2B3004383, NRF-2020M3D1A1110527]
  3. KU-KIST School Program
  4. National Research Foundation of Korea [2020M3D1A1110527, 2017M3D1A1039561] Funding Source: Korea Institute of Science & Technology Information (KISTI), National Science & Technology Information Service (NTIS)

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Carbonaceous and organic compounds are promising classes of SIB electrode materials due to their abundant constituent elements and reduced environmental impact. To accelerate their development for SIB applications, a thorough understanding of the charge storage mechanism is essential.
Sodium ion batteries (SIB) have received much research attention in the past decades as they are considered to be one alternative to the currently prevalent lithium ion batteries, and carbonaceous and organic compounds present two promising classes of SIB electrode materials advantaged by abundance of their constituent elements and reduced environmental footprints. To accelerate the development of these materials for SIB applications, future research directions must be guided by a thorough understanding of the charge storage mechanism. This review presents recent efforts in mechanism elucidation for these two classes of SIB electrode materials since, compared to their inorganic counterparts, they have unique challenges in material analysis. Topics covered will include characterization techniques and analytical frameworks for mechanism elucidation, emphasizing the advantages and limitations of individual experimental methodologies and providing a commentary on scientific rigor in result interpretation.

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