4.4 Article

Characterization and phenol adsorption performance of activated carbon prepared from tea residue by NaOH activation

Journal

ENVIRONMENTAL TECHNOLOGY
Volume 40, Issue 2, Pages 171-181

Publisher

TAYLOR & FRANCIS LTD
DOI: 10.1080/09593330.2017.1384069

Keywords

Tea residue; activated carbon; two-step pyrolysis; adsorption; phenol removal

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The preparation of activated carbon (AC) using tea residue was addressed in this work. The preparation process incorporated two-step pyrolysis and activation using NaOH. The influence of activation temperature between 500 degrees C and 700 degrees C on the properties of the AC sample was investigated. The physicochemical properties of the AC sample were characterized. The results show that the optimum temperature for the activation process is 700 degrees C, which generates the AC sample with higher specific surface area and total pore volume, respectively, of 819 m(2) g(-1) and 0.443 cm(3) g(-1). The oxygen-containing functional groups evolve on the AC sample during the activation process. The phenol adsorption test was performed to evaluate the adsorption performance of the AC sample. The adsorption data confirm that phenol adsorption on the AC sample obtained at 700 degrees C follows the pseudo-second-order kinetics model. Hereby, the electron donor-acceptor interaction mechanism can describe the adsorption process. The AC sample obtained at 700 degrees C performs superior phenol adsorption performance. The maximum phenol adsorption capacity is 320 mg g(-1), which is higher than that of several AC samples reported previously. Thus, the tea residue acts as a good precursor for the AC with promising adsorption capacity by the NaOH chemical activation method.

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