4.7 Article Proceedings Paper

The role of graphene oxide and graphene oxide-based nanomaterials in the removal of pharmaceuticals from aqueous media: a review

Journal

ENVIRONMENTAL SCIENCE AND POLLUTION RESEARCH
Volume 24, Issue 9, Pages 7938-7958

Publisher

SPRINGER HEIDELBERG
DOI: 10.1007/s11356-017-8388-8

Keywords

Graphene oxide; Graphene oxide-based nanomaterials; Water pollution cleanup; Adsorption; Interaction mechanism

Funding

  1. Chinese government under China Scholarship Council (CSC)
  2. NSFC [21225730, 91326202, 21577032]
  3. Fundamental Research Funds for the Central Universities [JB2015001]
  4. Kunlun Scholarship of Qinghai province
  5. Jiangsu Provincial Key Laboratory of Radiation Medicine and Protection
  6. Priority Academic Program Development of Jiangsu Higher Education Institutions

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In this review paper, the ill effects of pharmaceuticals (PhAs) on the environment and their adsorption on graphene oxide (GO) and graphene oxide-based (GO-based) nanomaterials have been summarised and discussed. The adsorption of prominent PhAs discussed herein includes beta-blockers (atenolol and propranolol), antibiotics (tetracycline, ciprofloxacin and sulfamethoxazole), pharmaceutically active compounds (carbamazepine) and analgesics such as diclofenac. The adsorption of PhAs strictly depends upon the experimental conditions such as pH, adsorbent and adsorbate concentrations, temperature, ionic strength, etc. To understand the adsorption mechanism and feasibility of the adsorption process, the adsorption isotherms, thermodynamics and kinetic studies were also considered. Except for some cases, GO and its derivatives show excellent adsorption capacities for PhAs, which is crucial for their applications in the environmental pollution cleanup.

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