4.4 Review

Recent Advances in the Syntheses of Helicene-Based Molecular Nanocarbons via the Scholl Reaction

Journal

CHINESE JOURNAL OF ORGANIC CHEMISTRY
Volume 41, Issue 11, Pages 4105-4137

Publisher

SCIENCE PRESS
DOI: 10.6023/cjoc202107063

Keywords

helicene; molecular nanocarbon; chiral materials; chiral nanocarbon; Scholl reaction; cyclization reaction

Funding

  1. National Natural Science Foundation of China [21901128, 22071120]
  2. National Key RAMP
  3. D Program of China [2020YFA0711500]
  4. Fundamental Research Funds for the Central Universities

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The review summarizes recent advances in the syntheses of helicene-based molecular nanocarbons via the Scholl reaction, showcasing their potential applications in various fields and offering perspectives to stimulate further development in chiral nanocarbon materials.
Molecular nanocarbon materials with well-defined structures constructed through organic synthesis have attracted much attention in recent years, exhibiting unique properties and broad applications in many areas. The combination of helicenes and molcular nanocarbons generates a fancinating type of chiral molecular nanocarbons with potential applications in the fields of chiral optics, chiral optoelectronics and spintronics etc. However, it is of greart challenge to synthesize these molecules due to the large intramolecular strain and the special helical structure. Among various synthetic strategies, the Scholl reaction possesses the advantages of mild conditions and high efficiency. In this review, recent advances in the syntheses of helicene-based molecular nanocarbons via the Scholl reaction are summarized, and our perspectives to stimulate further development of the chiral nanocarbon materials are also provided.

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