First-principles study of excitons in optical spectra of silver chloride

Silver chloride is a material that has been investigated and used for many decades. Of particular interest are its optical properties, but only few fundamental theoretical studies exist. We present first-principles results for the optical properties of AgCl, obtained using time-dependent density functional theory and many-body perturbation theory. We show that optical properties exhibit strong excitonic effects, which are correctly captured only by solving the Bethe-Salpeter equation starting from quasiparticle self-consistent GW results. Numerical simulations are made feasible by using a model screening for the electron-hole interaction in a way that avoids the calculation of the static dielectric constant. Finally, the localization of bright and dark excitons is discussed.

Automated summary

In this study, first-principles results for the optical properties of silver chloride were presented, showing strong excitonic effects that can only be correctly captured by solving the Bethe-Salpeter equation. Numerical simulations were made feasible by using a model screening for the electron-hole interaction, avoiding the calculation of the static dielectric constant. The localization of bright and dark excitons was also discussed.