4.5 Article

Porous V2O3@C composite anodes with pseudocapacitive characteristics for lithium-ion capacitors

Journal

NEW CARBON MATERIALS
Volume 36, Issue 6, Pages 1103-1108

Publisher

ELSEVIER
DOI: 10.1016/S1872-5805(21)60070-7

Keywords

V2O3; Lithium ion capacitor; Hybrid device; 3D porous carbon

Funding

  1. National Natural Science Foundation of China [51672151, 52172047]

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In this study, porous V2O3@C composites were prepared using a NaCl template-assisted freeze-drying strategy, showing high-rate pseudocapacitive behavior. The lithium-ion capacitor based on this composite exhibited high energy density, high power density, and long cycle stability, indicating great potential for high-performance LICs.
Vanadium trioxide materials have attracted great interest due to their low cost and high theoretical lithium storage capacity. In this work, porous V2O3@C composites were prepared via a NaCl template-assisted freeze-drying strategy. Benefiting from the unique three-dimensional porous carbon-based structure, the V2O3@C composite anode exhibits a high-rate pseudocapacitive behavior. A lithium-ion capacitor (LIC) based on this V2O3@C composite anode and a commercial AC cathode was constructed. Results show that the as-constructed device exhibits high energy density, high power density as well as long cycle stability, indicating the great promise of our porous V2O3@C composites for the high-performance LICs.

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