4.2 Article

5-ARYLIDENETETRONATE AS A VERSATILE ELECTROPHORE FOR PI-EXTENDED ELECTRON ACCEPTORS

Journal

HETEROCYCLES
Volume 103, Issue 1, Pages 165-171

Publisher

PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.3987/COM-20-S(K)2

Keywords

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Funding

  1. Programme Exploration Japon 2018 from the French Embassy in Tokyo
  2. CNRS
  3. Universite Lyon 1
  4. MEXT [2707]
  5. JSPS Japan [15H03790, 16K13968, JP19K15528]
  6. Japan Science Society
  7. Program of Five-star Alliance in NJRC Mater. Dev. MEXT
  8. Grants-in-Aid for Scientific Research [15H03790, 16K13968] Funding Source: KAKEN

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The Bis[4-methoxy-5-methylenefuran-2(5H)-one]-type electron acceptors prepared in this study exhibit reversible electrochemical reduction, indicating the potential of 5-arylidenetetronate as an electrophore for developing novel electron acceptors.
Bis[4-methoxy-5-methylenefuran-2(5H)-one]-type electron acceptors with anthracene-9,10-diyl and thiophene-2,5-diyl spacer were prepared by one-pot condensation of methyl tetronate with the corresponding dialdehydes. They undergo reversible electrochemical reduction, thus showing the potential utility of 5-arylidenetetronate as an electrophore for developing novel electron acceptors.

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