4.2 Article

AZIDO, CYANO, AND NITRATO CYCLIC HYPERVALENT IODINE(III) REAGENTS IN HETEROCYCLE SYNTHESIS

Journal

HETEROCYCLES
Volume 103, Issue 1, Pages 144-164

Publisher

PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.3987/REV-20-SR(K)5

Keywords

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Funding

  1. JSPS KAKENHI [JP20K06980, JP19K05466]
  2. Ritsumeikan Global Innovation Research Organization (R-GIRO) project

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Benziodoxol(on)es have shown to be useful synthetic tools for introducing heteroatoms in the preparation of functionalized heterocyclic compounds.
In recent years, synthetic applications of cyclic hypervalent iodine reagents have undergone significant developments. Among them, benziodoxol(on)es containing azido, cyano, and nitrato ligands have been found to be useful synthetic tools for the preparation of functionalized heterocyclic compounds. This review aims to summarize recent synthetic applications of benziodoxol(on)es as effective heteroatom-introducing reagents.

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