Journal
ACS MATERIALS LETTERS
Volume 3, Issue 12, Pages 1635-1651Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acsmaterialslett.1c00250
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Categories
Funding
- DFG [FOR2433]
- Fonds der Chemischen Industrie
- DFG through a COORNET [SPP1928]
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Studying the structural behavior of metal-organic frameworks under high pressures is a growing field focusing on identifying principles related to technological properties and material behaviors. Important aspects include rigorous reporting of experimental procedures, opportunities with customized high-pressure diffraction setups, the nature and impact of pressure-transmitting mediums, and strengthening the ties between computation and experimentation.
Studying the structural behavior of metal-organic frameworks ( MOFs) under hydrostatic pressures is a steadily growing area. The goal of active research is identification of overarching composition-structure principles including both properties of technological relevance and material behavior of academic interest such as material stability criteria, mechanical properties, pressure-induced phase transitions, negative compressibilities, and guest-dependent high-pressure structural responses. Here the current literature on the high-pressure structural responses of MOFs is reviewed with focus on bulk moduli, pressure-transmitting medium dependent properties, pressure-induced phase transitions, and amorphization processes-properties that are derived from high-pressure X-ray diffraction studies. After highlighting topical examples, aspects of high-pressure diffraction studies on MOFs are summarized that are important to advance the field such as the rigorous reporting of experimental and analytical procedures, opportunities that come with custom-made high-pressure diffraction setups, the nature and impact of the pressure-transmitting medium, and the role of forging even closer ties between computation and experiment.
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