Journal
ENERGY & ENVIRONMENTAL SCIENCE
Volume 10, Issue 8, Pages 1792-1800Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c7ee01096f
Keywords
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Funding
- Australian Government through the Australian Renewable Energy Agency (ARENA)
- Australian Research Council
- MSTC [2016YFA0301300]
- NNSFC [11674402]
- GSTP [201607010044, 201607020023]
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Interfacial carrier recombination is one of the dominant loss mechanisms in high efficiency perovskite solar cells, and has also been linked to hysteresis and slow transient responses in these cells. Here we demonstrate an ultrathin passivation layer consisting of a PMMA: PCBM mixture that can effectively passivate defects at or near to the perovskite/TiO2 interface, significantly suppressing interfacial recombination. The passivation layer increases the open circuit voltage of mixed-cation perovskite cells by as much as 80 mV, with champion cells achieving V-oc similar to 1.18 V. As a result, we obtain efficient and stable perovskite solar cells with a steady-state PCE of 20.4% and negligible hysteresis over a large range of scan rates. In addition, we show that the passivated cells exhibit very fast current and voltage response times of less than 3 s under cyclic illumination. This new passivation approach addresses one of the key limitations of current perovskite cells, and paves the way to further efficiency gains through interface engineering.
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