4.5 Review

Rare Earth Borohydrides-Crystal Structures and Thermal Properties

Journal

ENERGIES
Volume 10, Issue 12, Pages -

Publisher

MDPI
DOI: 10.3390/en10122115

Keywords

borohydrides; complex metal hydrides; rare earth; hydrogen storage; crystal structure; thermal properties; composites; reversibility

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Funding

  1. European Union [607040]
  2. Research Council of Norway through FRIENERGI project
  3. Research Council of Norway through SYNKNOYT program

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Rare earth (RE) borohydrides have received considerable attention during the past ten years as possible hydrogen storage materials due to their relatively high gravimetric hydrogen density. This review illustrates the rich chemistry, structural diversity and thermal properties of borohydrides containing RE elements. In addition, it highlights the decomposition and rehydrogenation properties of composites containing RE-borohydrides, light-weight metal borohydrides such as LiBH4 and additives such as LiH.

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