4.3 Article

Preparation of Bismuth Oxide Nanoplatelets/Si Photodetector by Laser Ablation in Liquid Under Effect of an External Magnetic Field

Journal

SILICON
Volume 14, Issue 1, Pages 107-113

Publisher

SPRINGER
DOI: 10.1007/s12633-020-00789-4

Keywords

Bi2O3; Nanoplatelets; Laser ablation; Photodetector

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In this study, the effect of applying magnetic field on Bi2O3 nanoparticles and Bi2O3/n-Si heterojunction photodetector was investigated. The results showed that the magnetic field altered the morphology and optical properties of the nanoparticles, and improved the performance of the heterojunction photodetector.
In this work, we have studied the effect of applying magnetic field on the properties of Bi2O3 nanoparticles and figures of merit of Bi2O3/n-Si heterojunction photodetector prepared by pulsed laser ablation in liquid (PLAL) technique. X-ray diffraction (XRD) results confirmed that the synthesized nanoparticles are polycrystalline in nature with alpha-Bi2O3 with monoclinic phase. Scanning electron microscope (SEM) revealed the formation of spherical nanoparticles for nanoparticles prepared without magnetic field with an average size of 24 nm, while the nanoparticles synthesized in the presence of magnetic field have platelets and nanoflowers morphologies. UV-Vis result showed that the optical energy gap of the nanoparticles decreased from 3.12 to 2.87 eV after applying the magnetic field during the ablation. The effect of applying the magnetic field on the figures of merit of the Bi2O3/n-Si photodetector was investigated. The responsivity of Bi2O3/n-Si heterojunction photodetectors increased from 0.3 to 0.9A/W at 660 nm after applying the magnetic field during the ablation.

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