Journal
JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY
Volume 147, Issue 11, Pages 6207-6217Publisher
SPRINGER
DOI: 10.1007/s10973-021-10953-6
Keywords
Phosphorus-nitrogen; SiO2; Polypropylene; Synergistic flame retardant; Gas and condensed phase
Funding
- NSFC [20774031, 21074039]
- Natural Science Foundation of Guangdong [2014A030313241, 2014B090901068, 2016A010103003]
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Through the synthesis and study of the MPHP flame retardant and its synergistic effect with SiO2 in PP, it was found that they can improve the flame retardancy and mechanical properties of the material.
An organic compound melamine phenyl hypophosphite (MPHP), containing phosphorus and nitrogen, was synthesized and characterized. Its flame retardant properties and synergistic flame retardancy with silicon dioxide (SiO2) on polypropylene (PP) was investigated. The limiting oxygen index (LOI) value of PP/30%MPHP reached 31.3%, and UL 94V-0 rating was attained. The LOI value of PP/27%MPHP/3%SiO2 reached 28.7%, and the peak heat release rate (pk-HRR) of PP/27%MPHP/3%SiO2 was 42.3% lower than that of pure PP. In addition, the flame retardant mechanism was investigated using scanning electron microscopy, X-ray diffraction, energy-dispersive X-ray, Fourier transform infrared spectroscopy and Pyrolysis-gas chromatography-mass spectrometry (PY-GC-MS). MPHP/SiO2 had synergistic flame retardant effect, and simultaneously exerted gas phase and condensed phase flame retardant effect. Adding a small amount of SiO2 to PP/MPHP, not only reduced the heat release rate, but also improved the mechanical properties.
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