Journal
REACTION CHEMISTRY & ENGINEERING
Volume 1, Issue 2, Pages 156-160Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c5re00009b
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Biocatalytic asymmetric reductions have been key steps in the enantioselective reduction of 1,1-dimethoxy-2-propanone, catalyzed by suitable ketoreductases, to enantiomerically pure (S)-and (R)-1,1-dimethoxy-2-propanols, obtained in >= 99.9% ee and excellent yield. Removal of the protecting group gave the (S)- and (R)-lactaldehydes in high yield and excellent enantiomeric and chemical purity.
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