Journal
ACS ORGANIC & INORGANIC AU
Volume 2, Issue 3, Pages 197-204Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acsorginorgau.1c00053
Keywords
intramolecular activation; hydrogen bonding; organocatalysis; metal catalysis; bifunctional catalysis; asymmetric synthesis
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Funding
- European Research Council [647550, 861930]
- Spanish Government [RTI2018-095038-B-I00]
- Comunidad de Madrid
- European Structural Funds [S2018/NMT-4367, Y2020/NMT-6469]
- European Research Council (ERC) [861930, 647550] Funding Source: European Research Council (ERC)
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The activation of molecules through intramolecular hydrogen-bond formation is an effective strategy in organic synthesis for enhancing reactivity, stabilizing chemical species, and controlling enantioselectivity.
The activation of molecules through intramolecular hydrogen-bond formation to promote chemical reactions appears as a suitable strategy in organic synthesis, especially for the preparation of chiral compounds under metal and organocatalytic conditions. The use of this interaction has enabled reactivity enhancement of reagents, as well as stabilization of the chemical species and enantiocontrol of the processes.
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