Journal
ATMOSPHERIC CHEMISTRY AND PHYSICS
Volume 22, Issue 2, Pages 1195-1208Publisher
COPERNICUS GESELLSCHAFT MBH
DOI: 10.5194/acp-22-1195-2022
Keywords
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Funding
- Academy of Finland [310682, 337550]
- European Union [821205, 730997]
- Academy of Finland (AKA) [310682, 337550, 310682] Funding Source: Academy of Finland (AKA)
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Accurate determination of gas-to-particle partitioning is crucial for modeling secondary organic aerosol formation. In this study, we estimated the saturation vapor pressures of alpha-pinene-ozonolysis-derived secondary organic aerosol constituents using experimental and computational methods. The results showed a good agreement between the two methods for molecules with molar masses around 190 g mol(-1) and higher.
Accurate information on gas-to-particle partitioning is needed to model secondary organic aerosol formation. However, determining reliable saturation vapor pressures of atmospherically relevant multifunctional organic compounds is extremely difficult. We estimated saturation vapor pressures of alpha-pinene-ozonolysis-derived secondary organic aerosol constituents using Filter Inlet for Gases and AEROsols (FIGAERO)-chemical ionization mass spectrometer (CIMS) experiments and conductor-like screening model for real solvents (COSMO-RS). We found a good agreement between experimental and computational saturation vapor pressures for molecules with molar masses around 190 g mol(-1) and higher, most within a factor of 3 comparing the average of the experimental vapor pressures and the COSMO-RS estimate of the isomer closest to the experiments. Smaller molecules likely have saturation vapor pressures that are too high to be measured using our experimental setup. The molecules with molar masses below 190 g mol(-1) that have differences of several orders of magnitude between the computational and experimental saturation vapor pressures observed in our experiments are likely products of thermal decomposition occurring during thermal desorption. For example, dehydration and decarboxylation reactions are able to explain some of the discrepancies between experimental and computational saturation vapor pressures. Based on our estimates, FIGAERO-CIMS can best be used to determine saturation vapor pressures of compounds with low and extremely low volatilities at least down to 10(-10) Pa in saturation vapor pressure.
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