Journal
CHINESE JOURNAL OF CATALYSIS
Volume 43, Issue 3, Pages 548-557Publisher
ELSEVIER
DOI: 10.1016/S1872-2067(21)63919
Keywords
Radical transformations; 1; 3-Dienes; Radical difunctionalization; Transition metal catalysis; Photoredox catalysis
Funding
- National Natural Science Foundation of China [91856119, 21971081, 21820102003, 91956201]
- Open Research Fund of School of Chemistry and Chemical Engineering, Henan Normal University [2021YB02]
- Excellent Doctoral Dissertation Cultivation Grant from CCNU
- Program of Introducing Talents of Discipline to Universities of China (111 Program) [B17019]
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This review critically illustrates the recent advances in radical-mediated transformations of 1,3-dienes based on different radical precursors and working modes. Special emphasis is given to the related mechanistic studies and synthetic applications.
1,3-Dienes are a class of easily accessible and versatile feedstock chemicals that can participate in a wide range of reactions to facilitate the synthesis of various valuable allylic compounds. In the past decades, radical methodology has emerged as a powerful tool for organic synthesis by virtue of the fact that diverse highly reactive radical species can usually be generated under mild, neutral and controlled conditions, and allow for rapid generation of molecular complexity. In this review, we critically illustrate the recent advances in the field of radical-mediated transformations of 1,3-dienes based on the different radical precursors and working modes. Wherever possible, particular emphasis is also put on the related mechanistic studies and synthetic applications. (c) 2022, Dalian Institute of Chemical Physics, Chinese Academy of Sciences. Published by Elsevier B.V. All rights reserved.
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