Magnetic properties of RuO 2 and charge-magnetic interference in Bragg diffraction of circularly polarized x-rays

Rutile-type RuO2 likely supports a simple antiferromagnetic structure which can be verified by x-ray Bragg diffraction. Three magnetic motifs that do not break translation symmetry are explored in calculations of amplitudes suitable for diffraction enhanced by tuning the primary x-ray energy to a ruthenium atomic resonance. Coupling to x-ray helicity through a charge-magnetic interference is common to all motifs, together with magnetic and charge intensities in quadrature in the rotated channel of polarization. Necessary conditions for these diffraction phenomena are a centrosymmetric crystal structure, null magnetic propagation vector, and absence of a linear magnetoelectric effect. Published x-ray diffraction data for RuO2 were analyzed by the authors against a magnetic motif that does not satisfy the conditions. A polarized neutron study of antiferromagnetic domains can be achieved with a sample that meets the stated crystal and magnetic symmetries.

Automated summary

This study examines the magnetic structure of rutile-type RuO2 and analyzes it using methods such as X-ray diffraction and polarized neutron study. The results indicate that the magnetic properties of rutile-type RuO2 can be described by a simple antiferromagnetic structure.