Journal
CHEMICAL COMMUNICATIONS
Volume 58, Issue 26, Pages 4196-4199Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/d2cc00424k
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Funding
- Spanish Ministry of Science, through the Severo Ochoa'' Programme for Centres of Excellence in RD [CEX2019-000917-S]
- Ministerio de Economia y Competitividad [PID2019-106832RB-I00, PID2020-116728RB-I00, CTQ2015-71955]
- Generalitat de Catalunya [2017SGR1720]
- DOC-FAM programme under the Marie Sklodowska-Curie grant [754397]
- Community of Madrid [S2018/NMT-4349]
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The use of metallacarboranes [3,3'-M(1,2-C2B9H11)(2)](-) (M = Co, Fe) as general internal reference systems in electrochemical processes has been studied. Their suitability has been proven by investigating their electrochemical properties in both aqueous and organic electrolytes without the need for derivatization.
Ferrocene and its derivatives have been extensively used as an internal reference in electrochemical processes. Yet, they possess limitations such as solvent restrictions that require chemical modifications. In this regard, we have studied the use of metallacarboranes [3,3 '-M(1,2-C2B9H11)(2)](-) (M = Co, Fe) as general internal reference systems and have proven their suitability by thoroughly investigating their electrochemical properties in both aqueous and organic electrolytes without any derivatization.
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