Journal
TRENDS IN CHEMISTRY
Volume 4, Issue 3, Pages 220-235Publisher
CELL PRESS
DOI: 10.1016/j.trechm.2021.12.005
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Funding
- National Natural Science Foundation of China [21925109, 21772170]
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Transition-metal-catalyzed enantioselective C-H bond activation is a crucial tool for the synthesis of complex chiral molecules. This review summarizes recent advances in Pd-catalyzed enantioselective C-H functionalization.
Transition-metal-catalyzed enantioselective C-H bond activation has emerged as an increasingly important tool for the expedient synthesis of complex chiral molecules. In the past decade, palladium, one of the most commonly employed metal catalysts, has attracted significant attention in enantioselective C-H functionalization for its great promise to streamline the synthesis of chiral molecules and inspired new retrosynthetic disconnections. This review highlights recent advances in Pd-catalyzed enantioselective C-H functionalization reactions with an emphasis on the catalytic pathways, types of chiral ligands, and chirality.
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