Journal
BIOSCIENCE BIOTECHNOLOGY AND BIOCHEMISTRY
Volume 86, Issue 2, Pages 170-176Publisher
OXFORD UNIV PRESS
DOI: 10.1093/bbb/zbab196
Keywords
Citrus junos; 6-methyloctanal; 8-methyldecanal; enantioselective synthesis; enantiomeric composition
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This study analyzed the characteristic aroma components of 6-methyloctanal and 8-methyldecanal in yuzu essential oil, and determined their absolute configurations and enantiomeric compositions.
6-Methyloctanal and 8-methyldecanal are the characteristic aroma components of yuzu Citrus junos. However, their absolute configurations and enantiomeric compositions in yuzu essential oil have not been analyzed. A concise enantioselective synthesis of both aldehydes was successfully carried out to determine their absolute configurations and enantiomeric compositions. Both aldehydes in yuzu essential oil were found to be (S)-form with high enantiomeric excess.
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