Journal
ORGANIC & BIOMOLECULAR CHEMISTRY
Volume 20, Issue 11, Pages 2200-2204Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/d2ob00168c
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- Building Blocks of Life program of NWO [737.016.006]
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Using a CoIII(salen)OTs catalyst, dibenzyl phosphate can selectively open a variety of terminal epoxides with high regio-selectivity and yields up to 85%. This reaction enables the efficient synthesis of enantiopure mixed-diacyl phosphatidic acids, including a photoswitchable phosphatidic acid mimic.
With a CoIII(salen)OTs catalyst, dibenzyl phosphate ring-opens a variety of terminal epoxides with excellent regio-selectively and yields up to 85%. The reaction is used in a highly efficient synthesis of enantiopure mixed-diacyl phosphatidic acids, including a photoswitchable phosphatidic acid mimic.
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