4.6 Article

Acid-base resistant ligand-modified molybdenum-sulfur clusters with enhanced photocatalytic activity towards hydrogen evolution

Related references

Note: Only part of the references are listed.
Review Chemistry, Physical

Current progress of metal sulfides derived from metal-organic frameworks for advanced electrocatalysis: potential electrocatalysts with diverse applications

Xuan Liu et al.

Summary: This review summarizes the recent progress of MOF-derived TMS electrocatalysts for hydrogen evolution reactions, oxygen evolution reactions, and oxygen reduction reactions, as well as discusses strategies to improve the performance of electrocatalysts and their bifunctional catalytic performances for overall water splitting and rechargeable Zn-air batteries. Challenges and opportunities for the future development of this field are also proposed in order to initiate more efforts and new discoveries in this emerging research area.

JOURNAL OF MATERIALS CHEMISTRY A (2022)

Article Chemistry, Multidisciplinary

[Mo3S13]2- as a Model System for Hydrogen Evolution Catalysis by MoSx: Probing Protonation Sites in the Gas Phase by Infrared Multiple Photon Dissociation Spectroscopy

Aristeidis Baloglou et al.

Summary: Materials based on molybdenum sulfide are efficient hydrogen evolution reaction (HER) catalysts, with [HMo3S13](-) serving as a molecular model system to study the binding site for H atoms. Through FT-ICR MS and IRMPD spectroscopy, one distinct S-H stretching vibration at 2450 cm(-1) was observed, providing evidence for a terminal disulfide unit as the H adsorption site based on thermochemical arguments and DFT calculations.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2021)

Review Nanoscience & Nanotechnology

Nanoscale engineering of catalytic materials for sustainable technologies

Sharon Mitchell et al.

Summary: Nanostructured materials play a crucial role in industrial catalysis, offering potential solutions to sustainability challenges. Researchers strive to control the properties of active sites on catalytic surfaces for optimized reactivity. Computational methods complement experimental approaches in advancing catalyst design.

NATURE NANOTECHNOLOGY (2021)

Article Chemistry, Multidisciplinary

Precise Implantation of an Archimedean Ag@Cu12 Cuboctahedron into a Platonic Cu4Bis(diphenylphosphino)hexane6 Tetrahedron

Bao-Liang Han et al.

Summary: The study isolated two similar heterometallic cluster-in-cage compounds through an antigalvanic reaction, providing more details for understanding the confined growth of atomically precise nanoclusters. The compounds can be deemed as molecular fragments excised from porous nanomaterials filled with discrete nanoclusters, shedding light on the binding and geometry matching between clusters and cages.

ACS NANO (2021)

Review Chemistry, Multidisciplinary

Cooperative Coupling of Oxidative Organic Synthesis and Hydrogen Production over Semiconductor-Based Photocatalysts

Ming-Yu Qi et al.

Summary: The review discusses the combination of hydrogen evolution with oxidative organic synthesis using a semiconductor-mediated photoredox reaction, showcasing a dual-functional photocatalytic strategy for constructing C-C/C-X bonds under green conditions. It emphasizes the cooperative photoredox coupling of selective organic synthesis and H-2 production over semiconductor catalysts, highlighting recent progress and future perspectives in this flourishing area. It is anticipated to provide guidance for the development of economically and environmentally benign solar fuel generation and organic synthesis of value-added fine chemicals.

CHEMICAL REVIEWS (2021)

Review Chemistry, Multidisciplinary

Shell engineering to achieve modification and assembly of atomically-precise silver clusters

Yan Jin et al.

Summary: This review summarizes the progress in the preparation and structural determination of monolayer-protected silver clusters, focusing on the strategies and methods for precise modification and hierarchical assembly of silver clusters through shell engineering. The correlations between structure-property and structure-functionality of silver clusters are discussed, with particular emphasis on the structure-luminescence relationship and the potential of silver clusters as lighting materials. The challenges and perspectives of functional silver clusters are also highlighted, aiming to inspire the development of functionality-oriented materials based on nanosized building blocks in the fields of nanotechnology and material science.

CHEMICAL SOCIETY REVIEWS (2021)

Article Multidisciplinary Sciences

Photocatalytic water splitting with a quantum efficiency of almost unity

Tsuyoshi Takata et al.

NATURE (2020)

Article Chemistry, Multidisciplinary

Stable Ti3+Defects in Oriented Mesoporous Titania Frameworks for Efficient Photocatalysis

Kun Lan et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2020)

Article Chemistry, Multidisciplinary

Photochemical In Situ Exfoliation of Metal-Organic Frameworks for Enhanced Visible-Light-Driven CO2Reduction

Hui-Li Zheng et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2020)

Article Chemistry, Physical

Photocatalytic coproduction of H2 and industrial chemical over MOF-derived direct Z-scheme heterostructure

Meng Liu et al.

APPLIED CATALYSIS B-ENVIRONMENTAL (2020)

Article Chemistry, Physical

[Mo3S13]2- modified TiO2 coating on non-woven fabric for efficient photocatalytic mineralization of acetone

Yu Han et al.

APPLIED CATALYSIS B-ENVIRONMENTAL (2019)

Article Chemistry, Multidisciplinary

A Molecular Cobalt Hydrogen Evolution Catalyst Showing High Activity and Outstanding Tolerance to CO and O2

Jia-Wei Wang et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2019)

Article Chemistry, Multidisciplinary

Isolated Square-Planar Copper Center in Boron Imidazolate Nanocages for Photocatalytic Reduction of CO2 to CO

Hai-Xia Zhang et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2019)

Article Multidisciplinary Sciences

A broadband and strong visible-light-absorbing photosensitizer boosts hydrogen evolution

Ping Wang et al.

NATURE COMMUNICATIONS (2019)

Article Chemistry, Multidisciplinary

Structural and Electronic Optimization of MoS2 Edges for Hydrogen Evolution

Hao Wang et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2019)

Review Chemistry, Multidisciplinary

Metal-Organic Frameworks for Photocatalysis and Photothermal Catalysis

Juan-Ding Xiao et al.

ACCOUNTS OF CHEMICAL RESEARCH (2019)

Article Chemistry, Inorganic & Nuclear

Photocatalytic H2-Evolution by Homogeneous Molybdenum Sulfide Clusters Supported by Dithiocarbamate Ligands

Patricia R. Fontenot et al.

INORGANIC CHEMISTRY (2019)

Review Chemistry, Multidisciplinary

Artificial photosynthesis: opportunities and challenges of molecular catalysts

Biaobiao Zhang et al.

CHEMICAL SOCIETY REVIEWS (2019)

Article Chemistry, Multidisciplinary

{Nb288O768(OH)48(CO3)12}: A Macromolecular Polyoxometalate with Close to 300 Niobium Atoms

Yan-Lan Wu et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2018)

Article Chemistry, Multidisciplinary

Rational Design of MOF/COF Hybrid Materials for Photocatalytic H2 Evolution in the Presence of Sacrificial Electron Donors

Feng-Ming Zhang et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2018)

Article Chemistry, Multidisciplinary

The Largest Supertetrahedral Oxychalcogenide Nanocluster and Its Unique Assembly

Huajun Yang et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2018)

Article Chemistry, Multidisciplinary

Linking Molybdenum-Sulfur Clusters for Electrocatalytic Hydrogen Evolution

Zhe Ji et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2018)

Article Chemistry, Multidisciplinary

Formation of Hierarchical Co9S8@ZnIn2S4 Heterostructured Cages as an Efficient Photocatalyst for Hydrogen Evolution

Sibo Wang et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2018)

Review Chemistry, Multidisciplinary

Casting a Wider Net: Rational Synthesis Design of Low-Dimensional Bulk Materials

Katherine A. Benavides et al.

ACCOUNTS OF CHEMICAL RESEARCH (2018)

Article Chemistry, Multidisciplinary

Engineering stepped edge surface structures of MoS2 sheet stacks to accelerate the hydrogen evolution reaction

Jue Hu et al.

ENERGY & ENVIRONMENTAL SCIENCE (2017)

Article Chemistry, Inorganic & Nuclear

Ligand Effect on the Single-Molecule Magnetism of Tetranuclear Co(II) Cubane

Xiong-Feng Ma et al.

INORGANIC CHEMISTRY (2017)

Article Chemistry, Multidisciplinary

Bandgap Engineering of Titanium-Oxo Clusters: Labile Surface Sites Used for Ligand Substitution and Metal Incorporation

Jin-Xiu Liu et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2016)

Article Chemistry, Multidisciplinary

Assembly of a Highly Stable Luminescent Zn5 Cluster and Application to Bio-Imaging

Ming-Hua Zeng et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2016)

Review Chemistry, Multidisciplinary

Two-dimensional layered MoS2: rational design, properties and electrochemical applications

Gong Zhang et al.

ENERGY & ENVIRONMENTAL SCIENCE (2016)

Article Chemistry, Multidisciplinary

Dimeric [Mo2S12]2- Cluster: A Molecular Analogue of MoS2 Edges for Superior Hydrogen-Evolution Electrocatalysis

Zhongjie Huang et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2015)

Article Chemistry, Multidisciplinary

Visible-Light Photoreduction of CO2 in a Metal-Organic Framework: Boosting Electron-Hole Separation via Electron Trap States

Hai-Qun Xu et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2015)

Review Chemistry, Multidisciplinary

Face the Edges: Catalytic Active Sites of Nanomaterials

Bing Ni et al.

ADVANCED SCIENCE (2015)

Review Chemistry, Multidisciplinary

Titanium Dioxide-Based Nanomaterials for Photocatalytic Fuel Generations

Yi Ma et al.

CHEMICAL REVIEWS (2014)

Article Multidisciplinary Sciences

A Molecular MoS2 Edge Site Mimic for Catalytic Hydrogen Generation

Hemamala I. Karunadasa et al.

SCIENCE (2012)

Article Chemistry, Multidisciplinary

Molybdenum-sulfur dimers as electrocatalysts for the production of hydrogen at low overpotentials

AM Appel et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2005)