A portable visual coffee ring based on carbon dot sensitized lanthanide complex coordination to detect bisphenol A in water

In this work, a ratiometric fluorescence sensor along with a portable coffee ring visualized detection method for bisphenol A (BPA) was developed based on carbon dots. The probe was formed by the coordination polymerization of Eu3+ and 5 '-adenosine monophosphate on the surface of carbon dots containing a large number of hydroxyl and carbonyl groups. The results showed that the fluorescence intensity ratio and the concentration of BPA had a good linear relationship in a wide range of 0.1-100 mu M with a detection limit of 20 nM (S/N = 3). The recoveries of the added standard BPA in water samples ranged from 91.80 to 102.7% with relative standard deviation values no more than 1.84% (n = 3). In addition, the changes of the fluorescence color of the CDs@Eu-AMP suspension with different BPA concentrations can be easily visualized under a UV lamp by the naked eye, which highlights the great potential of the coffee ring detection method for the fast and convenient monitoring of BPA in real water samples.

Automated summary

In this study, a colorimetric and fluorescence detection method based on carbon dots was developed for bisphenol A (BPA). The concentration of BPA was visualized by observing the color change of the fluorescence under a UV lamp, highlighting the potential of this method for the monitoring of BPA in real water samples.