Journal
CHEMISTRYSELECT
Volume 1, Issue 14, Pages 4246-4254Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/slct.201600845
Keywords
electron diffraction; nanostructures; oxides; transmission electron microscopy (TEM); x-ray diffraction
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This minireview intends to summarize the knowledge about the microstructure of the ceria based mixed oxides Ce(1-x)Ln(x)O(2-(x/2)). During the years, idea about the Ce(1-x)Ln(x)O(2-(x/2)) structure has been changed and evolved in to a complicated, beautiful but realistic model. Based on the literature data, the mechanism of F -> C structure transformation for Ce(1-x)Ln(x)O(2-(x/2)), with in-creasing of Ln(3+) -ions concentration, has been proposed. Traced the way to describe the beautiful structure of Ce(1-x)Ln(x)O(2-(x/2)), depending on the phase composition of the mixed oxide, could be very helpful for the design of new materials with interesting properties and potential technological applications.
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