4.6 Article

Synthesis of C-prenylated analogues of stilbenoid methyl ethers and their cyclic dihydrobenzopyranyl derivatives as potential anti-inflammatory agents

Journal

RSC ADVANCES
Volume 12, Issue 13, Pages 8188-8192

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/d2ra00441k

Keywords

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Funding

  1. Masaryk University Brno [MUNI/A/1682/2020]
  2. Czech Science Foundation [GF21-38204L]
  3. SustES-Adaptation strategies for sustainable ecosystem services and food security under adverse environmental conditions [CZ.02.1.01/0.0/0.0/16_019/0000797]
  4. Ministry of Education, Youth and Sports of CR within the CzeCOS program [LM2018123]

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An efficient and versatile synthesis method for the naturally occurring C-prenylated stilbenoid methyl ethers and their synthetic analogues is presented. The synthesis involves a six-step convergent process which includes an optimized C-prenylation method. Additionally, six new dihydro-benzopyranyl derivatives were obtained and isolated during the demethylation process.
An efficient and versatile synthesis of the naturally occurring C-prenylated stilbenoid methyl ethers and their synthetic analogues is presented. The synthesis represents a six step convergent process including an optimised C-prenylation method. Furthermore, during the demethylation process, six new dihydro-benzopyranyl derivatives were obtained and isolated.

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