☆ 4.8 Article

Electrolyte design implications of ion-pairing in low-temperature Li metal batteries

ENERGY & ENVIRONMENTAL SCIENCE (2022)

Related references

Note: Only part of the references are listed.

Review Chemistry, Physical

Emerging Era of Electrolyte Solvation Structure and Interfacial Model in Batteries

Haoran Cheng et al.

Summary: Recent research has shown that not only the solid-electrolyte interphase (SEI) layer but also the metal-ion solvation structure and interfacial model in the electrolyte significantly affect the performance of lithium-ion batteries. In this paper, the authors summarize recent studies on the importance of electrolyte solvation structure, develop a quantitative model, and propose an interfacial model to understand the electrode's performance. These findings may lead to a new era beyond the SEI and have implications for the design and improvement of LIBs.

ACS ENERGY LETTERS (2022)

Add to Collection

Article Chemistry, Multidisciplinary

Ether-Based Electrolyte Chemistry Towards High-Voltage and Long-Life Na-Ion Full Batteries

Hao-Jie Liang et al.

Summary: By rationally designing the solvation configuration, a fully coordinated ether-based electrolyte with strong resistance against oxidation is reported, demonstrating excellent stability and performance with high-voltage cathodes. The assembled full cells show superior rate performance, unprecedented cycling stability, and high energy density, indicating promising prospects for application.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2021)

Add to Collection

Article Chemistry, Physical

Cation-Dependent Interfacial Structures and Kinetics for Outer-Sphere Electron-Transfer Reactions

Botao Huang et al.

Summary: This study shows that the identity of spectator cation species can influence the solvation properties and ET kinetics of the redox species, with a trend of increasing solvent reorganization energy as cationic radius decreases. The presence of less charge density cations such as Cs+ can promote weaker hydrogen bonds and lower the effective interfacial static dielectric constant in the redox solvation shell, impacting reaction thermodynamics and rates in electrochemical processes.

JOURNAL OF PHYSICAL CHEMISTRY C (2021)

Add to Collection

Article Chemistry, Multidisciplinary

Correlating Li-Ion Solvation Structures and Electrode Potential Temperature Coefficients

Hansen Wang et al.

Summary: This study reveals the significant contribution of entropy change during the Li-ion desolvation process to the measured Li/Li+ electrode potential temperature coefficients. Relationships between electrode potential TCs and Li-ion solvation structures have been established and validated by ab initio molecular dynamics simulations, providing valuable insights for designing future electrolytes for Li-ion/Li metal batteries.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2021)

Add to Collection

Article Energy & Fuels

Tailoring electrolyte solvation for Li metal batteries cycled at ultra-low temperature

John Holoubek et al.

Summary: This study highlights the importance of the solvation structure of the electrolyte in charge-transfer behavior at ultra-low temperatures for lithium metal batteries. By designing an electrolyte to enable low-temperature operations, stable performance and high efficiency can be achieved for Li-metal batteries.

NATURE ENERGY (2021)

Add to Collection

Article Chemistry, Physical

Anion-Assisted Delivery of Multivalent Cations to Inert Electrodes

Artem Baskin et al.

Summary: By using free energy sampling techniques, it was found that anion solvophobicity promotes the delivery of species containing divalent cations to electrochemical interfaces, even to negatively charged electrodes. Additionally, cation desolvation is greatly facilitated by cation-anion coupling.

JOURNAL OF PHYSICAL CHEMISTRY LETTERS (2021)

Add to Collection

Article Chemistry, Physical

Ion-Dipole Chemistry Drives Rapid Evolution of Li Ions Solvation Sheath in Low-Temperature Li Batteries

Zhenxing Wang et al.

Summary: The sluggish evolution of lithium ions' solvation sheath can lead to dendrite formation and capacity loss in lithium batteries, especially at low temperatures. However, by using an ion-dipole strategy to regulate the fluorination degree of solvating agents, it is possible to accelerate the evolution of Li+ solvation sheath and improve battery performance. The DFEC-based electrolyte demonstrates significantly faster ion desolvation rate at low temperatures, allowing for better capacity retention in LiNi0.8Co0.1Mn0.1O2||lithium cells after cycling. This work provides a new technique towards rational design of electrolyte engineering for low-temperature lithium batteries.

ADVANCED ENERGY MATERIALS (2021)

Add to Collection

Review Green & Sustainable Science & Technology

Toward Low-Temperature Lithium Batteries: Advances and Prospects of Unconventional Electrolytes

Jinning Zhang et al.

Summary: By exploring unconventional electrolytes such as fluorinated ester and ethyl acetate, improvements in low-temperature lithium battery performance can be achieved, addressing the limitations of traditional carbonate-based electrolytes.

ADVANCED ENERGY AND SUSTAINABILITY RESEARCH (2021)

Add to Collection

Article Electrochemistry

Electrolyte Chemistry Towards Improved Cycling Stability in Na-Based Dual-Ion Batteries with High-Power/Energy Storage

Xian-Kun Hou et al.

Summary: Effective electrolyte design contributes to improved cycling stability, energy density, and overall performance of sodium-based DIBs, demonstrating the potential for high-power/energy applications and prolonged cycle life.

BATTERIES & SUPERCAPS (2021)

Add to Collection

Article Chemistry, Physical

Transient Voltammetry with Ultramicroelectrodes Reveals the Electron Transfer Kinetics of Lithium Metal Anodes

David T. Boyle et al.

ACS ENERGY LETTERS (2020)

Add to Collection

Article Chemistry, Physical

Localized High Concentration Electrolytes for High Voltage Lithium-Metal Batteries: Correlation between the Electrolyte Composition and Its Reductive/Oxidative Stability

Saul Perez Beltran et al.

CHEMISTRY OF MATERIALS (2020)

Add to Collection

Article Chemistry, Physical

Efficient Low-Temperature Cycling of Lithium Metal Anodes by Tailoring the Solid-Electrolyte Interphase

Akila C. Thenuwara et al.

ACS ENERGY LETTERS (2020)

Add to Collection

Editorial Material Multidisciplinary Sciences

Reining in dissolved transition-metal ions

Hooman Yaghoobnejad Asl et al.

SCIENCE (2020)

Add to Collection

Review Chemistry, Physical

Designing Advanced Lithium-Based Batteries for Low-Temperature Conditions

Abhay Gupta et al.

ADVANCED ENERGY MATERIALS (2020)

Add to Collection

Article Chemistry, Physical

A model for the effect of ion pairing on an outer sphere electron transfer

Renat Nazmutdinov et al.

PHYSICAL CHEMISTRY CHEMICAL PHYSICS (2020)

Add to Collection

Article Chemistry, Multidisciplinary

High-Energy Rechargeable Metallic Lithium Battery at-70°C Enabled by a Cosolvent Electrolyte

Xiaoli Dong et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2019)

Add to Collection

Article Chemistry, Physical

High-Concentration Ether Electrolytes for Stable High-Voltage Lithium Metal Batteries

Xiaodi Ren et al.

ACS ENERGY LETTERS (2019)

Add to Collection

Review Energy & Fuels

Pathways for practical high-energy long-cycling lithium metal batteries

Jun Liu et al.

NATURE ENERGY (2019)

Add to Collection

Review Energy & Fuels

Advances and issues in developing salt-concentrated battery electrolytes

Yuki Yamada et al.

NATURE ENERGY (2019)

Add to Collection

Article Energy & Fuels

High-energy lithium metal pouch cells with limited anode swelling and long stable cycles

Chaojiang Niu et al.

NATURE ENERGY (2019)

Add to Collection

Article Multidisciplinary Sciences

Role of solvent-anion charge transfer in oxidative degradation of battery electrolytes

Eric R. Fadel et al.

NATURE COMMUNICATIONS (2019)

Add to Collection

Article Energy & Fuels

Improving cyclability of Li metal batteries at elevated temperatures and its origin revealed by cryo-electron microscopy

Jiangyan Wang et al.

NATURE ENERGY (2019)

Add to Collection

Article Chemistry, Multidisciplinary

Distinct Nanoscale Interphases and Morphology of Lithium Metal Electrodes Operating at Low Temperatures

Akila C. Thenuwara et al.

NANO LETTERS (2019)

Add to Collection

Article Energy & Fuels

All-temperature batteries enabled by fluorinated electrolytes with non-polar solvents

Xiulin Fan et al.

NATURE ENERGY (2019)

Add to Collection

Article Chemistry, Physical

Enabling High-Voltage Lithium-Metal Batteries under Practical Conditions

Xiaodi Ren et al.

JOULE (2019)

Add to Collection

Article Chemistry, Physical

Accurate Determination of Coulombic Efficiency for Lithium Metal Anodes and Lithium Metal Batteries

Brian D. Adams et al.

ADVANCED ENERGY MATERIALS (2018)

Add to Collection

Review Chemistry, Multidisciplinary

Developing High-Performance Lithium Metal Anode in Liquid Electrolytes: Challenges and Progress

Sa Li et al.

ADVANCED MATERIALS (2018)

Add to Collection

Article Chemistry, Multidisciplinary

High-Voltage Lithium-Metal Batteries Enabled by Localized High-Concentration Electrolytes

Shuru Chen et al.

ADVANCED MATERIALS (2018)

Add to Collection

Article Electrochemistry

The use of lithium-ion batteries for JPL's Mars missions

Marshall C. Smart et al.

ELECTROCHIMICA ACTA (2018)

Add to Collection

Article Chemistry, Multidisciplinary

Highly Fluorinated Interphases Enable High-Voltage Li-Metal Batteries

Xiulin Fan et al.

CHEM (2018)

Add to Collection

Article Chemistry, Physical

Organic Batteries Operated at -70 degrees C

Xiaoli Dong et al.

JOULE (2018)

Add to Collection

Article Multidisciplinary Sciences

Liquefied gas electrolytes for electrochemical energy storage devices

Cyrus S. Rustomji et al.

SCIENCE (2017)

Add to Collection

Article Nanoscience & Nanotechnology

Li+-Desolvation Dictating Lithium-Ion Battery's Low-Temperature Performances

Qiuyan Li et al.

ACS APPLIED MATERIALS & INTERFACES (2017)

Add to Collection

Article Nanoscience & Nanotechnology

Wide-Temperature Electrolytes for Lithium-Ion Batteries

Qiuyan Li et al.

ACS APPLIED MATERIALS & INTERFACES (2017)

Add to Collection

Article Multidisciplinary Sciences

Lithium-ion battery structure that self-heats at low temperatures

Chao-Yang Wang et al.

NATURE (2016)

Add to Collection

Article Multidisciplinary Sciences

Superconcentrated electrolytes for a high-voltage lithium-ion battery

Jianhui Wang et al.

NATURE COMMUNICATIONS (2016)

Add to Collection

Article Multidisciplinary Sciences

High rate and stable cycling of lithium metal anode

Jiangfeng Qian et al.

NATURE COMMUNICATIONS (2015)

Add to Collection

Article Computer Science, Interdisciplinary Applications

XSEDE: Accelerating Scientific Discovery

John Towns et al.

COMPUTING IN SCIENCE & ENGINEERING (2014)

Add to Collection

Review Chemistry, Multidisciplinary

Lithium metal anodes for rechargeable batteries

Wu Xu et al.

ENERGY & ENVIRONMENTAL SCIENCE (2014)

Add to Collection

Article Electrochemistry

Heating strategies for Li-ion batteries operated from subzero temperatures

Yan Ji et al.

ELECTROCHIMICA ACTA (2013)

Add to Collection

Article Chemistry, Physical

Glyme-Lithium Salt Equimolar Molten Mixtures: Concentrated Solutions or Solvate Ionic Liquids?

Kazuhide Ueno et al.

JOURNAL OF PHYSICAL CHEMISTRY B (2012)

Add to Collection

Article Electrochemistry

The Effect of Additives upon the Performance of MCMB/LiNixCo1-xO2 Li-Ion Cells Containing Methyl Butyrate-Based Wide Operating Temperature Range Electrolytes

Marshall C. Smart et al.

JOURNAL OF THE ELECTROCHEMICAL SOCIETY (2012)

Add to Collection

Article Electrochemistry

Lithium-Ion Electrolytes Containing Ester Cosolvents for Improved Low Temperature Performance

M. C. Smart et al.

JOURNAL OF THE ELECTROCHEMICAL SOCIETY (2010)

Add to Collection

Article Chemistry, Physical

The low temperature performance of Li-ion batteries

SS Zhang et al.

JOURNAL OF POWER SOURCES (2003)

Add to Collection

© Peeref 2019-2024. All rights reserved.