4.7 Article

Phosphorescent biaryl platinum(iv) complexes obtained through double metalation of dibenzoiodolium ions

Related references

Note: Only part of the references are listed.
Article Chemistry, Inorganic & Nuclear

Strongly Luminescent Pt(IV) Complexes with a Mesoionic N-Heterocyclic Carbene Ligand: Tuning Their Photophysical Properties

Angela Vivancos et al.

Summary: A series of bis-cyclometalated Pt(IV) complexes incorporating mesoionic aryl-NHC ligand trz with either 1-phenylpyrazole or 2-arylpyridine ligands are reported, showing phosphorescent emissions in the blue to yellow color range with high quantum yields. The addition of trz ligand leads to lower nonradiative decay rates and higher quantum efficiencies compared to homologous species with two equal 2-arylpyridine ligands. Computational calculations substantiate the effect of the carbene ligand on the energy levels and emissive properties of the complexes.

INORGANIC CHEMISTRY (2021)

Article Chemistry, Inorganic & Nuclear

Luminescent halido(aryl) Pt(iv) complexes obtained via oxidative addition of iodobenzene or diaryliodonium salts to bis-cyclometalated Pt(ii) precursors

Juan-Carlos Lopez-Lopez et al.

Summary: The synthesis and photophysical properties of bis-cyclometalated halido(aryl) Pt(iv) complexes are reported. The introduction of aryl ligands through different methods and the comparison of chlorido and fluorido derivatives in terms of emission lifetimes and radiative rate constants are discussed. The study also highlights the role of radical species in the activation of solvents during the oxidative addition reaction.

DALTON TRANSACTIONS (2021)

Article Chemistry, Multidisciplinary

Bright Luminescent Platinum(II)-Biaryl Emitters Synthesized Without Air-Sensitive Reagents

Chuei Wakasugi et al.

CHEMISTRY-A EUROPEAN JOURNAL (2020)

Article Chemistry, Multidisciplinary

Stereoselective Formation of Facial Tris-Cyclometalated PtIVComplexes: Dual Phosphorescence from Heteroleptic Derivatives

Juan Carlos Lopez-Lopez et al.

CHEMISTRY-A EUROPEAN JOURNAL (2020)

Article Chemistry, Inorganic & Nuclear

Oxidative Addition of Biphenylene and Chlorobenzene to a Rh(CNC) Complex

Amy E. Kynman et al.

EUROPEAN JOURNAL OF INORGANIC CHEMISTRY (2020)

Article Chemistry, Inorganic & Nuclear

Highly Stable and Strongly Emitting N-Heterocyclic Carbene Platinum(II) Biaryl Complexes

Dominik Suter et al.

INORGANIC CHEMISTRY (2018)

Article Chemistry, Multidisciplinary

Developing strongly luminescent platinum(IV) complexes: facile synthesis of bis-cyclometalated neutral emitters

Fabio Julia et al.

CHEMICAL COMMUNICATIONS (2016)

Article Chemistry, Inorganic & Nuclear

Spotlight on the ligand: luminescent cyclometalated Pt(IV) complexes containing a fluorenyl moiety

Fabio Julia et al.

DALTON TRANSACTIONS (2016)

Article Chemistry, Inorganic & Nuclear

Influence of Ancillary Ligands and Isomerism on the Luminescence of Bis-cyclometalated Platinum(IV) Complexes

Fabio Julia et al.

INORGANIC CHEMISTRY (2016)

Article Chemistry, Multidisciplinary

Synthesis of Hemilabile Cyclic (Alkyl)(amino)carbenes (CAACs) and Applications in Organometallic Chemistry

Jiaxiang Chu et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2016)

Article Chemistry, Inorganic & Nuclear

Emissive Biphenyl Cyclometalated Gold(III) Diethyl Dithiocarbamate Complexes

Lakshmi Nilakantan et al.

ORGANOMETALLICS (2016)

Article Chemistry, Multidisciplinary

Oxidative Addition of Carbon-Carbon Bonds to Gold

Maximilian Joost et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2015)

Article Chemistry, Inorganic & Nuclear

HOMO-LUMO energy gap control in platinum(II) biphenyl complexes containing 2,2′-bipyridine ligands

D. Paul Rillema et al.

DALTON TRANSACTIONS (2015)

Article Multidisciplinary Sciences

Stable gold(III) catalysts by oxidative addition of a carbon-carbon bond

Chung-Yeh Wu et al.

NATURE (2015)

Article Chemistry, Multidisciplinary

A Detailed Study of Acetate-Assisted C-H Activation at Palladium(IV) Centers

Ansis Maleckis et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2013)

Article Chemistry, Multidisciplinary

Electrophilic fluorination of cationic Pt-aryl complexes

Shu-Bin Zhao et al.

CHEMICAL COMMUNICATIONS (2012)

Review Chemistry, Inorganic & Nuclear

The triplet state of organo-transition metal compounds. Triplet harvesting and singlet harvesting for efficient OLEDs

Hartmut Yersin et al.

COORDINATION CHEMISTRY REVIEWS (2011)

Article Chemistry, Multidisciplinary

C-H Bond Activation at Palladium(IV) Centers

Joy M. Racowski et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2011)

Article Chemistry, Inorganic & Nuclear

Stable and Tunable Phosphorescent Neutral Cyclometalated Au(III) Diaryl Complexes

Jai Anand Garg et al.

INORGANIC CHEMISTRY (2010)

Article Chemistry, Inorganic & Nuclear

Isolation of a Low-Coordinate Rhodium Phosphine Complex Formed by C-C Bond Activation of Biphenylene

Adrian B. Chaplin et al.

ORGANOMETALLICS (2010)

Article Chemistry, Inorganic & Nuclear

η2-Coordination and C-H activation of electron-poor arenes

CN Iverson et al.

ORGANOMETALLICS (2002)