Journal
CHEMICAL COMMUNICATIONS
Volume 58, Issue 28, Pages 4532-4535Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/d2cc01018f
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Funding
- Fundacion Seneca [19890/GERM/15]
- Ministerio de Ciencia, Innovacion y Universidades [PGC2018-100719-B-I00]
- Universidad de Murcia
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The first series of neutral, tris-chelate, phosphorescent Pt(IV) complexes, which combine specific ligands and react under mild conditions, were synthesized. The modulation of emission characteristics can be achieved by derivatization of the ligands.
The first series of neutral, tris-chelate, phosphorecent Pt(iv) complexes is reported, which combine two cyclometalated 2-arylpyridine ligands and a dimetalated biaryl. The introduction of biaryl ligands is achieved under mild conditions through the oxidative addition of dibenzoiodolium ions to Pt(ii) precursors to give Pt(iv) intermediates with a singly metalated 2-(2-iodoaryl)aryl ligand, followed by the reductive metalation of the C-I bond. The modulation of emission characteristics via derivatization of both types of ligands is demonstrated.
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