Journal
INFOMAT
Volume 4, Issue 6, Pages -Publisher
WILEY
DOI: 10.1002/inf2.12311
Keywords
electrochemical energy storage; multivalent ion batteries; open framework structures; Prussian-blue materials; rechargeable batteries
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Funding
- Experimental Center of Advanced Materials in Beijing Institute of Technology
- National Key R&D Program of China [2019YFA0705602]
- National Natural Science Foundation of China [51772029, 51972029]
- Shandong Huana New Energy Technology Co., Ltd.
- Teli Young Scholars of Beijing Institute of Technology
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This paper reviews the recent progress in the application of Prussian blue cathode materials for rechargeable batteries, including charge-storage mechanisms, factors influencing electrochemical performances, and possible approaches to overcome their intrinsic limitations.
The demand to increase energy density of rechargeable batteries for portable electronic devices and electric vehicles and to reduce the cost for grid-scale energy storage necessitates the exploration of new chemistries of electrode materials for rechargeable batteries. The open framework-structure of Prussian-blue materials has recently been demonstrated as a promising cathode host for a variety of monovalent and multivalent cations with the tunable working voltage and discharge capacities. Recent progress toward the application of Prussian-blue cathode materials for rechargeable batteries is reviewed, with special emphasis on charge-storage mechanisms of different insertion species, factors influencing electrochemical performances, and possible approaches to overcome their intrinsic limitations.
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