Rapid Pressureless Sintering of Glasses

Silica glasses have wide applications in industrial fields due to their extraordinary properties, such as high transparency, low thermal expansion coefficient, and high hardness. However, current methods of fabricating silica glass generally require long thermal treatment time (up to hours) and complex setups, leading to high cost and slow manufacturing speed. Herein, to obtain high-quality glasses using a facile and rapid method, an ultrafast high-temperature sintering (UHS) technique is reported that requires no additional pressure. Using UHS, silica precursors can be densified in seconds due to the large heating rate (up to 10(2) K s(-1)) of closely placed carbon heaters. The typical sintering time is as short as approximate to 10 s, approximate to 1-3 orders of magnitude faster than other methods. The sintered glasses exhibit relative densities of > 98% and high visible transmittances of approximate to 90%. The powder-based sintering process also allows rapid doping of metal ions to fabricate colored glasses. The UHS is further extended to sinter other functional glasses such as indium tin oxide (ITO)-doped silica glass, and other transparent ceramics such as Gd-doped yttrium aluminum garnet. This study demonstrates an UHS proof-of-concept for the rapid fabrication of high-quality glass and opens an avenue toward rapid discovery of transparent materials.

Automated summary

This study reports an ultrafast high-temperature sintering (UHS) technique for the rapid fabrication of high-quality silica glass. Using UHS, silica precursors can be densified within seconds, resulting in sintered glasses with high relative densities and high visible transmittances. The UHS technique can also be extended to sinter other functional glasses and transparent ceramics.