Journal
CHEMICAL COMMUNICATIONS
Volume 58, Issue 31, Pages 4849-4852Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/d2cc00936f
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Funding
- JST CREST [JPMJCR21O5]
- Cooperative Research Program of the ``Network Joint Research Center for Materials and Devices
- [JP21H04694]
- [JP18H02048]
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The facile synthesis and chiroptical properties of a new family of circularly polarized luminescence (CPL) materials, axially chiral 1,1 '-bicarbazolyls (BiCz), are reported. The BiCz derivatives emitted intense near-ultraviolet photoluminescence, with a peak at similar to 380 nm. The BiCz enantiomers showed mirror-image circular dichroism and CPL, with g(lum) values on the order of 10(-4) in solution.
The facile synthesis and chiroptical properties of a new family of circularly polarized luminescence (CPL) materials, axially chiral 1,1 '-bicarbazolyls (BiCz), are reported. The BiCz derivatives emitted intense near-ultraviolet photoluminescence, with a peak at similar to 380 nm. The BiCz enantiomers showed mirror-image circular dichroism and CPL, with g(lum) values on the order of 10(-4) in solution.
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