Journal
MATERIALS
Volume 15, Issue 6, Pages -Publisher
MDPI
DOI: 10.3390/ma15062034
Keywords
MoS2; B2O3; chemical exfoliation method; sintering techniques; lithium-ion batteries
Categories
Funding
- Korea Basic Science Institute (National Research Facilities and Equipment Center) - Ministry of Education [2019R1A6C1010016]
- Korea Basic Institute (National Research facilities and Equipment Center) - Ministry of Education [2020R1A6C103A050]
- National Research Foundation of Korea [2020R1A6C103A050] Funding Source: Korea Institute of Science & Technology Information (KISTI), National Science & Technology Information Service (NTIS)
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Molybdenum disulfide (MoS2) is a promising material for lithium storage applications, but its cycling performance can be reduced due to restructuring and sulfur dissolution. By decorating MoS2 nanosheets with B2O3 nanoparticles, the electrochemical performance and cycling stability can be improved.
Molybdenum disulfide (MoS2) is the most well-known transition metal chalcogenide for lithium storage applications because of its simple preparation process, superior optical, physical, and electrical properties, and high stability. However, recent research has shown that bare MoS2 nanosheet (NS) can be reformed to the bulk structure, and sulfur atoms can be dissolved in electrolytes or form polymeric structures, thereby preventing lithium insertion/desertion and reducing cycling performance. To enhance the electrochemical performance of the MoS2 NSs, B2O3 nanoparticles were decorated on the surface of MoS2 NSs via a sintering technique. The structure of B2O3 decorated MoS2 changed slightly with the formation of a lattice spacing of similar to 7.37 angstrom. The characterization of materials confirmed the formation of B2O3 crystals at 30% weight percentage of H3BO3 starting materials. In particular, the MoS2_B-3 sample showed a stable capacity of similar to 500 mAh.g(-1) after the first cycle. The cycling test delivered a high reversible specific capacity of similar to 82% of the second cycle after 100 cycles. Furthermore, the rate performance also showed a remarkable recovery capacity of similar to 98%. These results suggest that the use of B2O3 decorations could be a viable method for improving the stability of anode materials in lithium storage applications.
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