4.7 Article

Regiospecific construction of m-alkenyl benzaldehyde from β-bromoenal and vinyl borate

Journal

CHEMICAL COMMUNICATIONS
Volume 58, Issue 32, Pages 4989-4992

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/d2cc01441f

Keywords

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Funding

  1. NSFC [21772019, 21822303, 22003006]
  2. Venture and Innovation Support Program for Chongqing Overseas Returnees [cx2019007, cx2020047]

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In this study, a Pd-catalyzed regiospecific cycloaromatization of beta-bromoenal and vinyl borate esters is reported to synthesize m-alkenyl substituted benzaldehydes. This method allows the construction of complex molecules from simple materials and may be valuable in the search for new optical materials.
Herein, we report a Pd-catalyzed regiospecific cycloaromatization of beta-bromoenal and vinyl borate esters to synthesize m-alkenyl substituted benzaldehydes. This allows the construction of complex molecules from simple materials, which may be useful in the search for new optical materials.

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