Journal
DALTON TRANSACTIONS
Volume 51, Issue 15, Pages 5777-5781Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/d2dt00811d
Keywords
-
Categories
Funding
- MICINN/AEI
- ERDF A way of making Europe [CTQ2017-82893-C2-2-R]
- MICINN [CTQ2016-75193-P, PID2019-110856GA-I00]
- US/FEDER/JUNTA, UE [US126226]
- Junta de Andalucia [P18-FR-4688]
- MICINN
Ask authors/readers for more resources
In this study, Pt(ii) alkylidene 1a was reacted with terminal alkynes to form ylide complexes 3a-d through electrophilic activation and insertion. DFT calculations demonstrated that the observed regioselectivity is determined by the nucleophilic attack of the alkyne to the alkylidene carbon.
Pt(ii) alkylidene 1a has been reacted with terminal alkynes to afford ylide complexes 3a-d, resulting from electrophilic activation of the C= C bond and its insertion into the platinacyclic fragment of 1a that contains the carbene functionality. DFT calculations indicate that the observed regioselectivity is determined by the nucleophilic attack of the alkyne to the alkylidene carbon.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available