Journal
DALTON TRANSACTIONS
Volume 51, Issue 28, Pages 10714-10720Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/d2dt00582d
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Funding
- Deutsche Forschungsgemeinschaft (Emmy Noether program) [SCHA1915/3-1]
- Saarland University
- Deutsche Forschungsgemeinschaft [INST 256/506-1]
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The synthesis and characterization of bis(di-tert-butylindenyl) germanium(ii), tin(ii) and lead(ii) complexes were reported, including the first structurally authenticated example of a bis(indenyl)germanocene. The species were extensively studied in solution and in the solid state, revealing single crystal X-ray diffraction, NMR spectroscopy, and Mossbauer spectroscopy of the tin compound.
The synthesis and characterization of bis(di-tert-butylindenyl) germanium(ii), tin(ii) and lead(ii) complexes are reported, which includes the first structurally authenticated example of a bis(indenyl)germanocene. The species were studied in detail in solution and in the solid, which includes single crystal X-ray diffraction and NMR spectroscopy, as well as Mossbauer spectroscopy of the tin compound.
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