Journal
MATERIALS CHEMISTRY FRONTIERS
Volume 6, Issue 9, Pages 1228-1235Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/d2qm00077f
Keywords
-
Funding
- Key R&D plan of Jiangsu Province [BE20180051]
Ask authors/readers for more resources
In this study, an iridium(iii) terpyridine complex immobilized on a functionalized covalent triazine framework was demonstrated to be a highly effective catalyst for the acceptorless dehydrogenative coupling of o-aminobenzyl alcohols with ketones.
An iridium(iii) terpyridine complex Ir(tpy)@CTF, which is designed and synthesized by the coordinative immobilization of [Ir(tpy)Cl-3] on a functionalized covalent triazine framework, was proven to be a highly effective catalyst for the acceptorless dehydrogenative coupling of o-aminobenzyl alcohols with ketones. In the presence of the catalyst (1 mol% Ir), a range of desirable products were obtained in high yields. Moreover, the catalyst could be recycled without obvious loss of activity during six runs. Notably, this work exhibited the potential of covalent triazine framework-supported transition metal catalysts for acceptorless dehydrogenation.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available