4.7 Article

Visible-light photoredox catalysis-enabled borocyclopropanation of alkenes

Journal

ORGANIC CHEMISTRY FRONTIERS
Volume 9, Issue 10, Pages 2627-2633

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/d2qo00392a

Keywords

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Funding

  1. Natural Science Foundation of China [21702172]
  2. Department of Science & Technology of Sichuan Province [2019YJ0218]
  3. Fundamental Research Funds for the Central Universities [2682019CX75]
  4. 1000 talent program of Sichuan province
  5. student research training program (SRTP) [201910613075]

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A convenient method for the synthesis of cyclopropyl boronates via visible-light photoredox-catalyzed borocyclopropanation of alkenes is reported. The protocol shows wide substrate scope with regard to various substituted alkenes, good functional group tolerance, and mild reaction conditions, making it a striking approach.
Reported herein is a convenient method for the synthesis of cyclopropyl boronates via visible-light photoredox-catalyzed borocyclopropanation of alkenes. Its wide substrate scope with regard to various substituted alkenes, good functional group tolerance, mild reaction conditions and the ease of operation all constitute the striking features of this protocol.

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