Journal
CHEMICAL COMMUNICATIONS
Volume 58, Issue 32, Pages 5017-5020Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/d2cc00999d
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Funding
- Russian Science Foundation [20-73-00311]
- CNRS
- CALMIP [P18038]
- Ministry of Science and Higher Education of the Russian Federation
- French Embassy in Moscow
- Austrian Science Fund (FWF) [P18038] Funding Source: Austrian Science Fund (FWF)
- Russian Science Foundation [20-73-00311] Funding Source: Russian Science Foundation
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Low-temperature IR and NMR studies combined with DFT calculations revealed the mechanistic complexity of reactions between Mn(i) complex fac-[(dppm)Mn(CO)(3)H] and Lewis acids, involving the formation of mer-[(dppm)Mn(CO)(3)HMIDLINE HORIZONTAL ELLIPSISLA] and unusual dearomatization of the Ph3C+ cation upon hydride transfer.
Low-temperature IR and NMR studies combined with DFT calculations revealed the mechanistic complexity of apparently simple reactions between Mn(i) complex fac-[(dppm)Mn(CO)(3)H] and Lewis acids (LA = Ph3C+, B(C6F5)(3)) involving the formation of so-far elusive meridional hydride species mer-[(dppm)Mn(CO)(3)HMIDLINE HORIZONTAL ELLIPSISLA] and unusual dearomatization of the Ph3C+ cation upon hydride transfer.
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