4.7 Article

Fac-to-mer isomerization triggers hydride transfer from Mn(i) complex fac-[(dppm)Mn(CO)3H]

Journal

CHEMICAL COMMUNICATIONS
Volume 58, Issue 32, Pages 5017-5020

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/d2cc00999d

Keywords

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Funding

  1. Russian Science Foundation [20-73-00311]
  2. CNRS
  3. CALMIP [P18038]
  4. Ministry of Science and Higher Education of the Russian Federation
  5. French Embassy in Moscow
  6. Austrian Science Fund (FWF) [P18038] Funding Source: Austrian Science Fund (FWF)
  7. Russian Science Foundation [20-73-00311] Funding Source: Russian Science Foundation

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Low-temperature IR and NMR studies combined with DFT calculations revealed the mechanistic complexity of reactions between Mn(i) complex fac-[(dppm)Mn(CO)(3)H] and Lewis acids, involving the formation of mer-[(dppm)Mn(CO)(3)HMIDLINE HORIZONTAL ELLIPSISLA] and unusual dearomatization of the Ph3C+ cation upon hydride transfer.
Low-temperature IR and NMR studies combined with DFT calculations revealed the mechanistic complexity of apparently simple reactions between Mn(i) complex fac-[(dppm)Mn(CO)(3)H] and Lewis acids (LA = Ph3C+, B(C6F5)(3)) involving the formation of so-far elusive meridional hydride species mer-[(dppm)Mn(CO)(3)HMIDLINE HORIZONTAL ELLIPSISLA] and unusual dearomatization of the Ph3C+ cation upon hydride transfer.

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