Journal
CHEMICAL COMMUNICATIONS
Volume 58, Issue 42, Pages 6223-6226Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/d2cc01745h
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Funding
- National Natural Science Foundation of China [92161102, 21971118]
- Natural Science Foundation of Tianjin City [20JCYBJC01560, B2021202077]
- R. Gaurth Hansen Professorship fund
- Centre for High Performance Computing at the University of Utah
- FONDECYT [1221676]
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This work presents the synthesis of a naked tin cluster anion, Sn-36(8-), which represents the first example of a pure tin nanowire assembled through oxidative coupling reactions of a superatomic cluster, Sn-9(4-). Theoretical analysis confirms the presence of aromaticity for each Sn-9 unit, with four adjacent aromatic subunits bridged by parallel Sn-Sn bonds.
In this work, we synthesize naked tin cluster anion Sn-36(8-), representing the first example of pure Sn nanowire assembled through oxidative coupling reactions of a super atomic cluster Sn-9(4-). Theoretical analysis confirm the presence of aromaticity for each Sn-9 unit showing four adjacent aromatic subunits bridged by parallel Sn-Sn bonds.
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