4.8 Review

Porphyrinoid actinide complexes

Related references

Note: Only part of the references are listed.
Article Chemistry, Physical

Computational Study of Actinyl Ion Complexation with Dipyriamethyrin Macrocyclic Ligands

Elumalai Varathan et al.

Summary: Relativistic density functional theory was used to study [AnO(2)(L)](0/-1) complexes with actinide metals (U, Np, Pu, Am) and a hexa-aza porphyrin analogue ligand. Shorter axial and longer equatorial bond lengths were observed with a decrease in oxidation state from An(VI) to An(V). The actinide to pyrrole nitrogen bonds played a dominant role in complex formation, with significant ligand-to-metal charge transfer. The formation energy trend in gas-phase and dichloromethane solution followed the order UO2L > PuO2L > NpO2 L > AmO2 L, with negative ΔG and ΔH values. Energy decomposition analysis revealed a predominance of electrostatic over covalent interactions in both pentavalent and hexavalent actinyl complexes, with decreasing covalent character from U to Am.

JOURNAL OF PHYSICAL CHEMISTRY A (2021)

Review Chemistry, Physical

Comprehensive review of photophysical parameters (ε, Φf, τs) of tetraphenylporphyrin (H2TPP) and zinc tetraphenylporphyrin (ZnTPP) - Critical benchmark molecules in photochemistry and photosynthesis

Masahiko Taniguchi et al.

Summary: Tetraphenylporphyrin (H2TPP) and zinc tetraphenylporphyrin (ZnTPP) are widely used benchmark molecules with rich visible-region spectra and broad structural analogy to chlorophylls, but there is a significant variability in literature values for key photophysical parameters. A comprehensive review of 871 publications from 1940 to September 2020 found that the choice of values for parameters such as molar absorption coefficient, fluorescence quantum yield, and singlet excited-state lifetime can have far-reaching consequences in photochemistry applications. Different instrumentation and sources of error contribute to the wide range of reported values for these parameters.

JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY C-PHOTOCHEMISTRY REVIEWS (2021)

Article Chemistry, Multidisciplinary

Actinide Coordination Chemistry on Surfaces: Synthesis, Manipulation, and Properties of Thorium Bis(porphyrinato) Complexes

Erik Rheinfrank et al.

Summary: The method of synthesizing actinide-based metal-organic complexes on different surfaces was investigated, and analysis using various characterization methods demonstrated the potential functionality and application prospects of these structures.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2021)

Article Chemistry, Inorganic & Nuclear

Porphyrinoid f-Element Complexes

James T. Brewster et al.

INORGANIC CHEMISTRY (2020)

Article Chemistry, Multidisciplinary

Structural Diversity of F-Element Monophthalocyanine Complexes

Wen Zhou et al.

CHEMISTRY-A EUROPEAN JOURNAL (2020)

Review Chemistry, Inorganic & Nuclear

Recent advances in phthalocyanines for chemical sensor, non-linear optics (NLO) and energy storage applications

Denisha Gounden et al.

COORDINATION CHEMISTRY REVIEWS (2020)

Review Chemistry, Inorganic & Nuclear

Phthalocyanines for dye-sensitized solar cells

Maxence Urbani et al.

COORDINATION CHEMISTRY REVIEWS (2019)

Review Chemistry, Inorganic & Nuclear

Metal complexes of corrole

Sara Nardis et al.

COORDINATION CHEMISTRY REVIEWS (2019)

Article Chemistry, Multidisciplinary

In-Plane Thorium(IV), Uranium(IV), and Neptunium(IV) Expanded Porphyrin Complexes

James T. Brewster et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2019)

Article Chemistry, Multidisciplinary

UO22+-mediated ring contraction of pyrihexaphyrin: synthesis of a contracted expanded porphyrin-uranyl complex

James T. Brewster et al.

CHEMICAL SCIENCE (2019)

Article Multidisciplinary Sciences

Porphyrins inactivate Nosema spp. microsporidia

Aneta A. Ptaszynska et al.

SCIENTIFIC REPORTS (2018)

Review Chemistry, Multidisciplinary

Chemistry of meso-Aryl-Substituted Expanded Porphyrins: Aromaticity and Molecular Twist

Takayuki Tanaka et al.

CHEMICAL REVIEWS (2017)

Article Chemistry, Inorganic & Nuclear

Naphthylbipyrrole-Containing Amethyrin Analogue: A New Ligand for the Uranyl (UO22+) Cation

Gonzalo Anguera et al.

INORGANIC CHEMISTRY (2017)

Article Chemistry, Multidisciplinary

Synthesis and characterization of a dipyriamethyrin-uranyl complex

James T. Brewster et al.

CHEMICAL COMMUNICATIONS (2017)

Article Chemistry, Physical

Assessing covalency in equatorial U-N bonds: density based measures of bonding in BTP and isoamethyrin complexes of uranyl

Poppy Di Pietro et al.

PHYSICAL CHEMISTRY CHEMICAL PHYSICS (2016)

Article Chemistry, Inorganic & Nuclear

Reducing zirconium(IV) phthalocyanines and the structure of a Pc4-Zr complex

Wen Zhou et al.

DALTON TRANSACTIONS (2015)

Article Biotechnology & Applied Microbiology

Engineered porphyrin loaded core-shell nanoparticles for selective sonodynamic anticancer treatment

Greta Varchi et al.

NANOMEDICINE (2015)

Article Chemistry, Multidisciplinary

Reactivity of Rare Earth Metal Porphyrins/Phthalocyanines in Acid Media

Tatyana N. Lomova et al.

MACROHETEROCYCLES (2015)

Review Chemistry, Inorganic & Nuclear

Theoretical insights into the chemical bonding in actinide complexes

Jean-Pierre Dognon

COORDINATION CHEMISTRY REVIEWS (2014)

Article Chemistry, Multidisciplinary

A Hybrid Macrocycle with a Pyridine Subunit Displays Aromatic Character upon Uranyl Cation Complexation

I-Ting Ho et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2014)

Review Chemistry, Multidisciplinary

Phthalocyanine Metal Complexes in Catalysis

Alexander B. Sorokin

CHEMICAL REVIEWS (2013)

Review Chemistry, Multidisciplinary

A voyage into the synthesis and photophysics of homo- and heterobinuclear ensembles of phthalocyanines and porphyrins

Gema de la Torre et al.

CHEMICAL SOCIETY REVIEWS (2013)

Article Chemistry, Inorganic & Nuclear

Theoretical insights into covalency driven f element separations

Lindsay E. Roy et al.

DALTON TRANSACTIONS (2013)

Editorial Material Chemistry, Inorganic & Nuclear

Preface: Forum on Aspects of Inorganic Chemistry Related to Nuclear Energy

John C. Gordon et al.

INORGANIC CHEMISTRY (2013)

Article Chemistry, Multidisciplinary

Synthesis and Characterization of Thorium(IV) and Uranium(IV) Corrole Complexes

Ashleigh L. Ward et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2013)

Article Chemistry, Multidisciplinary

Superazaporphyrins: Meso-Pentaazapentaphyrins and One of Their Low-Symmetry Derivatives

Taniyuki Furuyama et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2012)

Review Chemistry, Multidisciplinary

Recent advances in computational actinoid chemistry

Dongqi Wang et al.

CHEMICAL SOCIETY REVIEWS (2012)

Review Chemistry, Inorganic & Nuclear

Recent advances in computational modeling and simulations on the An(III)/Ln(III) separation process

Jian-Hui Lan et al.

COORDINATION CHEMISTRY REVIEWS (2012)

Article Chemistry, Multidisciplinary

Cyclo[m]pyridine[n]pyrroles: Hybrid Macrocycles That Display Expanded π-Conjugation upon Protonation

Zhan Zhang et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2012)

Review Chemistry, Multidisciplinary

Expanded Porphyrins: Intriguing Structures, Electronic Properties, and Reactivities

Shohei Saito et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2011)

Article Chemistry, Multidisciplinary

Nitration of iron corrolates: further evidence for non-innocence of the corrole ligand

Manuela Stefanelli et al.

CHEMICAL COMMUNICATIONS (2011)

Article Chemistry, Multidisciplinary

Oxidative Nucleophilic Substitution of Hydrogen in the Sapphyrin Dioxouranium(VI) Complex: A Relativistic DFT Study

Grigory A. Shamov

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2011)

Review Chemistry, Multidisciplinary

Theoretical Actinide Molecular Science

Georg Schreckenbach et al.

ACCOUNTS OF CHEMICAL RESEARCH (2010)

Review Chemistry, Multidisciplinary

Aromaticity and photophysical properties of various topology-controlled expanded porphyrins

Jae-Yoon Shin et al.

CHEMICAL SOCIETY REVIEWS (2010)

Article Chemistry, Inorganic & Nuclear

Redox behavior of cyclo[6]pyrrole in the formation of a uranyl complex

Patricia J. Melfi et al.

INORGANIC CHEMISTRY (2007)

Review Chemistry, Multidisciplinary

Multicoordinate ligands for actinide/lanthanide separations

Henk H. Dam et al.

CHEMICAL SOCIETY REVIEWS (2007)

Article Chemistry, Multidisciplinary

Synthesis and characterization of double and triple decker uranium porphyrins

TN Lomova et al.

MENDELEEV COMMUNICATIONS (2003)

Article Chemistry, Multidisciplinary

Formation and properties of cyclo[6]pyrrole and cyclo[7]pyrrole

T Köhler et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2003)

Review Chemistry, Multidisciplinary

Recent developments in computational actinide chemistry

N Kaltsoyannis

CHEMICAL SOCIETY REVIEWS (2003)

Article Chemistry, Inorganic & Nuclear

Characterization of the interactions between neptunyl and plutonyl cations and expanded porphyrins

JL Sessler et al.

INORGANICA CHIMICA ACTA (2002)

Article Chemistry, Inorganic & Nuclear

Coexisting intraligand fluorescence and phosphorescence of hafnium(IV) and thorium(IV) porphyrin complexes in solution

G Knor et al.

INORGANIC CHEMISTRY COMMUNICATIONS (2002)

Article Chemistry, Inorganic & Nuclear

Actinide expanded porphyrin complexes

JL Sessler et al.

COORDINATION CHEMISTRY REVIEWS (2001)

Article Chemistry, Inorganic & Nuclear

New chemistry of amethyrin

S Hannah et al.

INORGANICA CHIMICA ACTA (2001)

Article Chemistry, Physical

Delocalization of electrons in molecules

R Herges et al.

JOURNAL OF PHYSICAL CHEMISTRY A (2001)

Article Chemistry, Inorganic & Nuclear

Synthesis and structural investigation of iodine doped uranium diphthalocyanine-UPc2I2

J Janczak et al.

INORGANICA CHIMICA ACTA (2000)