Journal
CRYSTENGCOMM
Volume 24, Issue 18, Pages 3317-3331Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/d2ce00190j
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Funding
- National Natural Science Foundation of China [21861012, 52062005]
- Natural Science Foundation of Guizhou Education Commission [2018148]
- Guizhou Science & Technology Commission [20201Z005, 20191157, 2021326, 20201Y163, 20181173]
- Doctoral Scientific Research Foundation of Suzhou University [2021BSK007]
- Scientific Research Platform Project of Suzhou University [2021XJPT08]
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The integration of polyoxometalates (POMs) with metal-alkynyl clusters has led to significant advances in the field, resulting in stabilized and functionalized clusters with promising applications.
Coinage metal-alkynyl clusters have been developed rapidly over the past few decades. An attractive area of this field is the integration of polyoxometalates (POMs) to direct the formation of metal-alkynyl clusters. POMs are metal-oxide clusters with unique structural diversity and tunable properties, and by incorporation of POM anions into the skeleton, the resulting clusters could be stabilized, functionalized, and so on. Herein, we summarize the advances in POM-based homo and heterometallic copper/silver-alkynyl clusters.
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