Journal
DALTON TRANSACTIONS
Volume 51, Issue 17, Pages 6543-6546Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/d2dt00962e
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- JST SPRING [JPMJSP2132]
- Fukuoka Naohiko Memorial Foundation
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This article describes the synthesis of a new stable compound PhMe2Si-B(dan) and its application in catalytic silylboration and silylation reactions of alkynes.
A new dimethyl(phenyl)silylborane having a naphthalene-1,8-diaminato (dan) substituent on the boron center, PhMe2Si-B(dan), was synthesized. Owing to the diminished boron Lewis acidity, it is highly stable toward air. Synthetic application of the silylborane to catalytic silylboration and silylation of alkynes is also described.
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