Journal
CHEMICAL COMMUNICATIONS
Volume 58, Issue 42, Pages 6255-6258Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/d2cc00847e
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Funding
- European Research Council (ERC) under the European Union [802727]
- European Research Council (ERC) [802727] Funding Source: European Research Council (ERC)
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This study demonstrates the anion binding and anion transport properties of a series of calix[6]arenes decorated with halogen bond or hydrogen bond donating groups on their small rim. The results show that the halogen bond donating iodotriazole groups enable highly selective transport of chloride and nitrate anions, without the transport of protons or hydroxide.
Here we present the anion binding and anion transport properties of a series of calix[6]arenes decorated on their small rim with either halogen bond or hydrogen bond donating groups. We show that the halogen bond donating iodotriazole groups enable highly selective transport of chloride and nitrate anions, without transport of protons or hydroxide, at rates similar to those observed with thiourea or squaramide groups.
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