Recent Progress in Direct Catalytic C(sp3)-H Silylation Reactions

Organosilicon compounds containing C(sp(3))-Si bonds are widely used in many research fields, such as material science, pharmaceutical chemistry and fine chemical synthesis. In recent years, due to its high atomic economy and step economy properties, the direct catalytic silylation of C(sp(3))-H bonds to form C(sp(3))-Si bonds has become one of the research hotspots in the syntheis of new organosilicones containing C(sp(3))-Si bonds. The research progress of direct catalytic silylation of C(sp(3))-H bonds is summarized in detail, and the mechanism and application range of related silylation reactions are also discussed.

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This article summarizes the research progress of direct catalytic silylation of C(sp(3))-H bonds and discusses the mechanism and application range of related reactions.