Journal
CHEMNANOMAT
Volume 2, Issue 10, Pages 980-988Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/cnma.201600185
Keywords
crystal growth; dye-sensitized solar cells; mesoporous materials; self-assembly; synthesis design
Categories
Funding
- Strategic Projects Program of Canada's Natural Sciences & Engineering Research Council
- Targray Technology Int'l
- 5N Plus Inc.
- CIS Scientific
- McGill Engineering Doctoral Award
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Mesoporous TiO2 rutile particles with a cauliflower-like morphology and an internal structure of self-assembled nanoneedles were synthesized in a novel Ti-IV chloride aqueous-solution hydrolysis process. In an effort to make nanostructured rutile synthesis cost-effective and green, the process was conducted at steady-state in a continuously stirred tank reactor (CSTR) below 100 degrees C. High TiCl4 concentration 0.5-1m yielded rutile, while lowering the concentration to 0.1m led to the crystallization of brookite nanoplatelets. Apart from phase control, specific surface area of rutile may be tuned via TiCl4 concentration regulation from 85 to 500 m(2)g(-1). Investigation revealed that low pH/high TiIV concentration conditions favored direct nucleation of rutile nuclei during steady state that grow radially outward into nanoneedle structured cauliflower particles with nanoscale edgy surface. The unique steady-state produced mesoporous rutile particles were shown to have excellent light scattering properties in a bi-layer photoanode structure resulting in 42.5% increase in photovoltaic efficiency. Brookite nanoplatelets were shown, in addition to their scattering properties, to exhibit stable Li-ion intercalation functionality.
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