Journal
JOURNAL OF MATERIALS CHEMISTRY A
Volume 10, Issue 20, Pages 11268-11276Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/d2ta00660j
Keywords
-
Funding
- National Natural Science Foundation of China [21772091, 21472092]
- Priority Academic Program Development of Jiangsu Higher Education Institutions
- Innovation Training Program for College Students in Jiangsu Province [202110287135Y]
Ask authors/readers for more resources
In this study, a novel copper loaded nitrogen-rich mesoporous carbon nitride material was designed and synthesized as a highly efficient photocatalyst for the selective cleavage of inert C-C bonds of amines under blue light irradiation. With the use of benign oxidant oxygen, good to excellent yields were achieved for various functionalized amines at room temperature, including sluggish aliphatic amines. This method offers a cost-effective and environmentally friendly alternative for the direct oxidative cleavage of amines.
Catalytic selective cleavage reaction of the C(sp(3))-C(sp(3)) bond has received little attention, despite its importance in organic synthesis and biochemistry. Herein, a novel copper loaded nitrogen-rich mesoporous carbon nitride material was designed and synthesized, and utilized as a highly efficient photocatalyst for the inert C-C bond cleavage of amines under blue light irradiation. With oxygen as a benign oxidant, good to excellent yields were achieved for various functionalized amines at room temperature, even including sluggish aliphatic amines. The method may provide a cost-effective and environmentally friendly alternative for the direct oxidative cleavage of amines.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available