4.2 Article

Molybdenum disulfide grafted titania nanotube arrays as high capacity retention anode material for lithium ion batteries

Journal

APPLIED NANOSCIENCE
Volume 7, Issue 1-2, Pages 67-73

Publisher

SPRINGER HEIDELBERG
DOI: 10.1007/s13204-016-0543-x

Keywords

Molybdenum disulfide; Titanium dioxide nanotube arrays; Anode material; Lithium-ion batteries

Funding

  1. National Natural Science Foundation of China [21271114]
  2. Tsinghua University independent research and development fund [20111080982]
  3. Program for Changjiang Scholars and Innovative Research Team in University [IRT13026]

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Titania nanotube arrays (TNAs) were grown by anodic oxidation method, and molybdenum disulfide (MoS2) grafted TNAs have been synthesized via one-step hydrothermal process. The MoS2 grafted TNAs (MoS2/TNAs) when employed as an anode material in lithium ion battery, exhibited excellent areal specific capacity (similar to 430 mu Ah cm(-2)) at current density of 50 mu A cm(-2), which is 33% higher as compared to the pure anatase TNAs and 55% higher as compared to MoS2. Moreover, the capacity loss per cycle of MoS2/TNAs (similar to 0.21%) was significantly lower than anatase TNAs (similar to 1.47%), suggesting an increase of capacity retention.

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