4.6 Review

Strategies for boosting the activity of single-atom catalysts for future energy applications

Related references

Note: Only part of the references are listed.
Article Chemistry, Physical

Ultrafast Joule heating synthesis of hierarchically porous graphene-based Co-N-C single-atom monoliths

Lingli Xing et al.

Summary: In this study, a transient heating-quenching strategy triggered by Joule heating was developed to synthesize single-atom cobalt- and nitrogen-doped graphene materials with a three-dimensional porous monolithic architecture. The resulting material exhibited high catalytic activity and durability for the hydrogen evolution reaction, showcasing the potential of this rapid and facile route for manufacturing single atom catalysts.

NANO RESEARCH (2022)

Article Nanoscience & Nanotechnology

Scalable two-step annealing method for preparing ultra-high-density single-atom catalyst libraries

Xiao Hai et al.

Summary: A general approach combining wet-chemistry impregnation and two-step annealing enables the scalable synthesis of ultra-high-density single-atom catalysts with metal contents up to 23 wt%, showcasing significantly enhanced reactivity. This method allows for the exploration of a vast library of mono- or multimetallic catalysts with tunable metal loadings.

NATURE NANOTECHNOLOGY (2022)

Article Nanoscience & Nanotechnology

Abrading bulk metal into single atoms

Gao-Feng Han et al.

Summary: A solvent-free and zero-waste method for synthesizing single-atom catalysts from bulk metals has been reported. This method is applicable to different metals and supports, and it offers a green and efficient approach for the commercialization of single-atom catalysts.

NATURE NANOTECHNOLOGY (2022)

Review Chemistry, Multidisciplinary

Recent Advances in Catalytic Hydrosilylations: Developments beyond Traditional PlatinumCatalysts

Leandro Duarte de Almeida et al.

Summary: This minireview discusses the use of homogeneous noble metal catalysts and earth-abundant transition metals/heterogeneous catalysts in hydrosilylation reactions, highlighting the growing interest in more sustainable and economic catalysts.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2021)

Review Chemistry, Physical

Synthesis of High Metal Loading Single Atom Catalysts and Exploration of the Active Center Structure

Kaiying Wang et al.

Summary: Single-atom catalysts (SACs) have emerged as a new frontier in catalysis field due to their highest atom utilization efficiency and tunable electronic structures, showing distinct catalytic performance from bulk counterparts. Strategies involving appropriate substrate, construction of coordination site, and spatial confinement are essential for preparing SACs with high metal loading. Advanced characterization techniques with atomic resolution are crucial for identifying the exact structure of SACs and developing in situ/operando techniques for atomic level characterization. Understanding the active center structure is fundamental for designing efficient SACs with maximum single-atom catalytic activity, and there are challenges and prospects for further development of SACs highlighted in this Review.

CHEMCATCHEM (2021)

Article Chemistry, Multidisciplinary

Iodine-Doping-Induced Electronic Structure Tuning of Atomic Cobalt for Enhanced Hydrogen Evolution Electrocatalysis

Jianbin Liu et al.

Summary: Iodine doping effectively modulates the electronic structure of single-atom catalysts, improving the catalytic activity of cobalt-nitrogen-carbon catalyst towards the hydrogen evolution reaction. The introduction of iodine dopants optimizes hydrogen adsorption and facilitates HER kinetics, providing an alternative strategy for enhancing SAC performance.

ACS NANO (2021)

Review Chemistry, Multidisciplinary

Synthesis Strategies, Catalytic Applications, and Performance Regulation of Single-Atom Catalysts

Jiangbo Xi et al.

Summary: Research on isolated metal atoms, specifically single-atom catalysis, has grown dramatically in recent years, drawing scientific interest. Single-atom catalysts (SACs) have high activity and other desirable properties that can be further enhanced by tuning their structures and interactions with support materials.

ADVANCED FUNCTIONAL MATERIALS (2021)

Article Chemistry, Multidisciplinary

Single-Atom-Layer Catalysis in a MoS2 Monolayer Activated by Long-Range Ferromagnetism for the Hydrogen Evolution Reaction: Beyond Single-Atom Catalysis

Hengli Duan et al.

Summary: Doping Co ions to induce long-range ferromagnetic order in single-layer MoS2 activates the majority of basal sites, enabling higher hydrogen evolution reaction activity on a single-layer of ferromagnetic MoS2.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2021)

Review Chemistry, Multidisciplinary

Understanding Doping of Quantum Materials

Alex Zunger et al.

Summary: Doping mobile carriers into ordinary semiconductors is crucial in electronic and optoelectronic revolutions, while the emergence of quantum materials with unique quantum interactions has drawn attention. The atomistic electronic structure theory of doping has recently been extended and applied to quantum materials.

CHEMICAL REVIEWS (2021)

Review Chemistry, Multidisciplinary

MOFs-Derived Carbon-Based Metal Catalysts for Energy-Related Electrocatalysis

Tongzhou Wang et al.

Summary: Electrochemical devices show great potential for sustainable development, but the lack of efficient electrocatalysts hinders their practical applications. Metal-organic frameworks (MOFs) derived catalysts with tunable structures and high activity have been intensively studied. These catalysts have shown promising applications in energy-related electrocatalysis such as hydrogen evolution, oxygen evolution, oxygen reduction, carbon dioxide reduction, and nitrogen reduction reactions.

SMALL (2021)

Article Multidisciplinary Sciences

Integrating single-cobalt-site and electric field of boron nitride in dechlorination electrocatalysts by bioinspired design

Yuan Min et al.

Summary: In this study, a single-atomic-site Co catalyst supported by BCN was reported to simulate reductive dehalogenases, showing high activity and selectivity in CAP dechlorination compared to other catalysts. The Co SAs/BCN catalyst exhibited enhanced stability and efficiency, making it a promising candidate for sustainable organic chloride conversion.

NATURE COMMUNICATIONS (2021)

Article Chemistry, Multidisciplinary

Green Synthesis of a Highly Efficient and Stable Single-Atom Iron Catalyst Anchored on Nitrogen-Doped Carbon Nanorods for the Oxygen Reduction Reaction

Xilong Wang et al.

Summary: In this study, a single-atom iron electrocatalyst Fe-SA/NCS was synthesized, showing excellent catalytic activity and stability for the oxygen reduction reaction in both acidic and alkaline media. This catalyst exhibited outstanding electrochemical performance in zinc-air batteries, indicating its promising applications in sustainable energy technologies.

ACS SUSTAINABLE CHEMISTRY & ENGINEERING (2021)

Article Chemistry, Multidisciplinary

Pulsed Laser Confinement of Single Atomic Catalysts on Carbon Nanotube Matrix for Enhanced Oxygen Evolution Reaction

Sukhyun Kang et al.

Summary: A promising method to synthesize single atom catalysts on highly conductive multiwall carbon nanotube supports using pulsed laser confinement process was reported. Incorporating cobalt and phosphorus atoms allows for superior catalytic performance in water oxidation reaction compared to benchmark RuO2 catalyst. Total processing time for assembling these catalysts via PLC process is less than 60 minutes, indicating promising practical applications.

ACS NANO (2021)

Article Chemistry, Multidisciplinary

Non-Bonding Interaction of Neighboring Fe and Ni Single-Atom Pairs on MOF-Derived N-Doped Carbon for Enhanced CO2 Electroreduction

Long Jiao et al.

Summary: Through the direct pyrolysis of MOFs assembled with Fe and Ni-doped ZnO nanoparticles, a novel Fe-1-Ni-1-N-C catalyst with neighboring Fe and Ni single-atom pairs on nitrogen-doped carbon support has been precisely constructed. The synergism of neighboring Fe and Ni single-atom pairs significantly boosts the electrocatalytic reduction of CO2, surpassing catalysts with separate Fe or Ni single atoms. The study reveals the importance of the communicative effect between adjacent single atoms for improved catalysis in single-atom catalysts containing multiple metal species.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2021)

Article Chemistry, Multidisciplinary

Soluble/MOF-Supported Palladium Single Atoms Catalyze the Ligand-, Additive-, and Solvent-Free Aerobic Oxidation of Benzyl Alcohols to Benzoic Acids

Estefania Tiburcio et al.

Summary: Palladium single atoms can be spontaneously formed in neat benzyl alcohols and used for organic oxidation reactions without additives or solvents. By stabilizing Pd SACs within a metal-organic framework, a solid catalyst was successfully prepared and characterized.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2021)

Article Chemistry, Multidisciplinary

Single-Atom-Based Heterojunction Coupling with Ion-Exchange Reaction for Sensitive Photoelectrochemical Immunoassay

Ying Qin et al.

Summary: Single-atom catalysts, especially platinum single atoms (Pt SAs), show great potential in catalyst design, with Pt SAs supported by nanomaterials demonstrating superior performance, particularly in photoelectrochemical biosensing, enhancing detection sensitivity for specific analytes.

NANO LETTERS (2021)

Article Chemistry, Physical

Ru1Con Single-Atom Alloy for Enhancing Fischer-Tropsch Synthesis

Ge Meng et al.

Summary: This study designed a Ru1Con single-atom alloy catalyst to improve FTS activity and long-chain hydrocarbon selectivity. Experimental and theoretical calculations showed that the Ru single-atom sites were more active for the FTS reaction due to their higher electronic density near the Fermi level, which effectively reduced the rate-limiting barriers of both C-O splitting and chain growth processes.

ACS CATALYSIS (2021)

Article Chemistry, Multidisciplinary

Short-Range Ordered Iridium Single Atoms Integrated into Cobalt Oxide Spinel Structure for Highly Efficient Electrocatalytic Water Oxidation

Jieqiong Shan et al.

Summary: This study proposes a method to integrate noble metal atoms into the lattice of transition metal oxides to create a new type of hybrid structure, showing that iridium single atoms can be effectively accommodated into cobalt spinel oxide. The resultant catalyst exhibits significantly higher electrocatalytic activity under acidic conditions, with improved corrosion resistance and oxidative potentials. This work eliminates the close-packing limitation of noble metals and offers promising opportunities for creating analogues with desired topologies for various catalytic applications.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2021)

Article Chemistry, Multidisciplinary

Tailoring Acidic Oxygen Reduction Selectivity on Single-Atom Catalysts via Modification of First and Second Coordination Spheres

Cheng Tang et al.

Summary: This study demonstrates that the molecular-level local structure, including first and second coordination spheres, plays a critical role in determining the selectivity of catalytic reactions. By modifying the first and second coordination spheres of Co-SACs, it is possible to tailor the oxygen reduction reaction selectivity. The unique selectivity change originates from the structure-dependent shift of active sites, leading to improved activity and selectivity for acidic H2O2 electrosynthesis.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2021)

Article Multidisciplinary Sciences

Rational strain engineering of single-atom ruthenium on nanoporous MoS2 for highly efficient hydrogen evolution

Kang Jiang et al.

Summary: This study utilizes strain engineering to amplify the synergistic effect between MoS2's sulfur vacancies and single-atom Ru sites, leading to accelerated H-2 evolution electrocatalysis.

NATURE COMMUNICATIONS (2021)

Article Chemistry, Physical

Tuning Charge Distribution of FeN4 via External N for Enhanced Oxygen Reduction Reaction

Yiyang Lin et al.

Summary: In this study, external N species, including pyrrolic-N and graphitic-N, were introduced near FeN4 to regulate its charge distribution and improve its ORR activity. Theoretical calculations and experimental results confirmed that the introduction of pyrrolic-N led to enhanced electron redistribution and local electrical field on the Fe site, resulting in positive charge accumulation and improved catalytic performance for ORR. This work provides guidance on enhancing the catalytic performances of single-atom catalysts by introducing charge-redistribution sites.

ACS CATALYSIS (2021)

Review Chemistry, Physical

The promise of hydrogen production from alkaline anion exchange membrane electrolyzers

Changqing Li et al.

Summary: Producing hydrogen using anion exchange membrane water electrolysis is a promising approach to address the energy crisis, but further understanding and improvement of the technology is needed, including increasing power efficiency and reducing costs.

NANO ENERGY (2021)

Article Chemistry, Multidisciplinary

Surface Electronic Modulation with Hetero-Single Atoms to Enhance Oxygen Evolution Catalysis

Feng Li et al.

Summary: The study successfully activated an inefficient oxygen evolution catalyst using a simple single atom tailoring strategy, achieving significantly enhanced catalytic activity. By implanting Rh element into a Cu oxide matrix, hetero-Rh single atom migration was achieved, leading to a more favorable oxygen evolution process.

ACS NANO (2021)

Review Chemistry, Multidisciplinary

Recent Developments of Microenvironment Engineering of Single-Atom Catalysts for Oxygen Reduction toward Desired Activity and Selectivity

Longbin Li et al.

Summary: Single-atom catalysts show great potential in oxygen reduction reaction, but microenvironment regulation is necessary to enhance their activity and selectivity. This review presents the mechanisms, evaluation, and characterization of SAAS, along with strategies for microenvironment modulation to improve performance. It also discusses future directions and challenges in ORR SACs.

ADVANCED FUNCTIONAL MATERIALS (2021)

Article Chemistry, Multidisciplinary

Integrating Single Atoms with Different Microenvironments into One Porous Organic Polymer for Efficient Photocatalytic CO2 Reduction

Xiao-Yu Dong et al.

Summary: The study introduced a series of porous organic polymers containing well-defined M-N-4 and M-N2O2 single-atom sites for CO2 conversion. The Ni-N2O2 moiety was identified as a more active site compared to the traditional Ni-N-4 moiety, effectively reducing the energy barrier and improving charge transportation for CO2 reduction. This work provides insights for designing more efficient single-atom catalysts toward CO2 reduction by modifying their coordination environments.

ADVANCED MATERIALS (2021)

Article Chemistry, Multidisciplinary

Decarboxylation-Induced Defects in MOF-Derived Single Cobalt Atom@Carbon Electrocatalysts for Efficient Oxygen Reduction

Shuai Yuan et al.

Summary: The study focuses on developing transition metal single-atom catalysts (SACs) for the oxygen reduction reaction (ORR) by using a decarboxylation-induced defects strategy to enhance their intrinsic activity. A gas-transport method was used to produce defective Co SACs (Co@DMOF) from carboxylate/amide mixed-linker MOF (DMOF), showing improved ORR activity compared to Co@ZIF-8-900.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2021)

Article Chemistry, Multidisciplinary

Ball-Milling Induced Debonding of Surface Atoms from Metal Bulk for Construing High-Performance Dual-Site Single-Atom Catalysts

Huilin Wang et al.

Summary: A high-performance catalyst Co-SNC was developed by introducing sulfur atoms into the key positions of the coordination environment, exhibiting high conversion and selectivity in benzylamine coupling reaction. Density functional theory calculations revealed the crucial role of sulfur atoms in activating O-2, leading to significantly increased adsorption energies and enhanced catalytic performance through delicately integrating dual active sites.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2021)

Article Chemistry, Multidisciplinary

Modulating Coordination Environment of Single-Atom Catalysts and Their Proximity to Photosensitive Units for Boosting MOF Photocatalysis

Xing Ma et al.

Summary: A general and facile strategy for the construction of high-loading single-atom catalysts with a tunable coordination microenvironment has been developed based on metal-organic frameworks. The well-accessible and atomically dispersed metal sites possess close proximity to photosensitive units, greatly accelerating charge transfer and promoting photocatalysis. The optimized Ni-1-S/MOF with a unique Ni(I) microenvironment presents excellent photocatalytic H-2 production activity, surpassing other counterparts.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2021)

Article Chemistry, Multidisciplinary

General synthesis of single-atom catalysts with high metal loading using graphene quantum dots

Chuan Xia et al.

Summary: A general method was reported for synthesizing single-atom catalysts with high transition-metal-atom loadings, showing significant improvements compared to benchmarks in the literature. The use of graphene quantum dots interwoven into a carbon matrix provided anchoring sites for high densities of transition-metal atoms without aggregation. An increase in activity was demonstrated in electrochemical CO2 reduction on a Ni single-atom catalyst with increased Ni loading.

NATURE CHEMISTRY (2021)

Article Chemistry, Physical

Chemical vapour deposition of Fe-N-C oxygen reduction catalysts with full utilization of dense Fe-N4 sites

Li Jiao et al.

Summary: Replacing scarce and expensive platinum with metal-nitrogen-carbon (M-N-C) catalysts for the oxygen reduction reaction in proton exchange membrane fuel cells has been impeded by the low active site density and site utilization of M-N-C. These limitations have now been overcome by implementing trans-metalation of Zn-N-4 sites into Fe-N-4 sites.

NATURE MATERIALS (2021)

Article Chemistry, Multidisciplinary

Fe-Ni Alloy Nanoclusters Anchored on Carbon Aerogels as High-Efficiency Oxygen Electrocatalysts in Rechargeable Zn-Air Batteries

Hong Li et al.

Summary: Fe-Ni ANC@NSCA catalysts anchored on N, S co-doped carbon aerogel were successfully prepared by optimal pyrolysis of polyaniline aerogels derived from the freeze-drying of PANI hydrogels obtained by the polymerization of aniline monomers in the co-presence of tannic acid, Fe3+, and Ni2+ ions. These catalysts showed excellent performance in both oxygen reduction reaction and oxygen evolution reaction, surpassing state-of-the-art commercial catalysts.

SMALL (2021)

Article Multidisciplinary Sciences

Electronic metal-support interaction modulates single-atom platinum catalysis for hydrogen evolution reaction

Yi Shi et al.

Summary: Tuning the oxidation states of single-atom Pt catalysts through electronic metal-support interaction significantly modulates catalytic activities in either acidic or alkaline environments, establishing the structure-activity relationship and providing guidelines for the rational design of high-performance single-atom catalysts. Insights into the atomic-level mechanistic understanding of acidic and alkaline hydrogen evolution reactions have been obtained through this study.

NATURE COMMUNICATIONS (2021)

Article Energy & Fuels

High-performing commercial Fe-N-C cathode electrocatalyst for anion-exchange membrane fuel cells

Horie Adabi et al.

Summary: This study presents a high-performing commercial oxygen reduction catalyst that can replace platinum group metal catalysts, resulting in improved performance and reduced cost for anion-exchange membrane fuel cells.

NATURE ENERGY (2021)

Article Chemistry, Physical

Interface dynamics of Pd-CeO2 single-atom catalysts during CO oxidation

Valery Muravev et al.

Summary: In this study, two Pd/CeO2 single-atom catalysts for low-temperature CO oxidation were compared, revealing the impact of preparation method on their stability. Detailed in situ characterization linked the stability of the Pd single atoms to the properties of the Pd-CeO2 interface. Understanding such metal-support interactions is crucial for the rational design of stable single-atom catalysts.

NATURE CATALYSIS (2021)

Article Chemistry, Physical

Edge-hosted Fe-N3 sites on a multiscale porous carbon framework combining high intrinsic activity with efficient mass transport for oxygen reduction

Jingjing Liu et al.

Summary: The designed Fe-N/C catalyst demonstrates high intrinsic activity with edge effects and enriched nanopores for improved mass transport efficiency and atom utilization. This study opens up new opportunities for designing high-performance ORR electrocatalysts for diverse energy conversion and storage technologies.

CHEM CATALYSIS (2021)

Article Chemistry, Multidisciplinary

Encapsulating Ultrastable Metal Nanoparticles within Reticular Schiff Base Nanospaces for Enhanced Catalytic Performance

Xinchun Yang et al.

Summary: The controllable fabrication of ultrasmall, highly dispersed, and functionalized metal nanoparticles is crucial for industrial applications. By using a metal-Schiff base template approach, highly enhanced catalytic activity and durability in the methanolysis of ammonia borane were achieved, with a turnover frequency (TOF) value of 177 min(-1) at 303 K.

CELL REPORTS PHYSICAL SCIENCE (2021)

Review Chemistry, Multidisciplinary

Cooperativity in supported metal single atom catalysis

Philippe Serp

Summary: This article highlights the importance of the support in single-atom catalysis, as factors beyond metal-support interaction can also impact the activity, selectivity, and stability of SAs. Different types of cooperativity, both specific and non-specific to SA catalysis, enable previously impossible reaction pathways on supported metal SAs.

NANOSCALE (2021)

Review Chemistry, Physical

Recent advances in single-atom electrocatalysts supported on two-dimensional materials for the oxygen evolution reaction

Yanan Zhou et al.

Summary: The oxygen evolution reaction (OER) is a major bottleneck in the electrolytic water-splitting for hydrogen generation due to its sluggish kinetics. Constructing single-atom catalysts (SACs) on two-dimensional materials has become an important research direction to enhance OER performance.

JOURNAL OF MATERIALS CHEMISTRY A (2021)

Review Chemistry, Multidisciplinary

Non-carbon-supported single-atom site catalysts for electrocatalysis

Xiaobo Zheng et al.

Summary: This review comprehensively summarizes the recent exciting progress on non-carbon-supported SACs and their applications in electrocatalytic reactions. Eight types of non-carbon-supported SACs are categorized to show their diversity, with detailed analysis of the anchoring and stabilization mechanisms. Advanced characterization techniques for identifying and monitoring the atomic structure of SACs are highlighted, along with discussions on their applications in electrochemical energy conversion.

ENERGY & ENVIRONMENTAL SCIENCE (2021)

Review Chemistry, Multidisciplinary

Designing Atomic Active Centers for Hydrogen Evolution Electrocatalysts

Yongpeng Lei et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2020)

Article Chemistry, Multidisciplinary

Uniformity Is Key in Defining Structure-Function Relationships for Atomically Dispersed Metal Catalysts: The Case of Pt/CeO2

Joaquin Resasco et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2020)

Article Chemistry, Multidisciplinary

Constructing High-Loading Single-Atom/Cluster Catalysts via an Electrochemical Potential Window Strategy

Jin-Cheng Liu et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2020)

Article Multidisciplinary Sciences

Uncovering near-free platinum single-atom dynamics during electrochemical hydrogen evolution reaction

Shi Fang et al.

NATURE COMMUNICATIONS (2020)

Article Multidisciplinary Sciences

Turning main-group element magnesium into a highly active electrocatalyst for oxygen reduction reaction

Shuai Liu et al.

NATURE COMMUNICATIONS (2020)

Article Multidisciplinary Sciences

Electrochemical deposition as a universal route for fabricating single-atom catalysts

Zhirong Zhang et al.

NATURE COMMUNICATIONS (2020)

Article Chemistry, Multidisciplinary

Coordination Tunes Selectivity: Two-Electron Oxygen Reduction on High-Loading Molybdenum Single-Atom Catalysts

Cheng Tang et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2020)

Review Chemistry, Multidisciplinary

Chemical Synthesis of Single Atomic Site Catalysts

Shufang Ji et al.

CHEMICAL REVIEWS (2020)

Review Chemistry, Multidisciplinary

Heterogeneous Single-Atom Photocatalysts: Fundamentals and Applications

Chao Gao et al.

CHEMICAL REVIEWS (2020)

Article Multidisciplinary Sciences

Strong metal-support interaction promoted scalable production of thermally stable single-atom catalysts

Kaipeng Liu et al.

NATURE COMMUNICATIONS (2020)

Article Chemistry, Multidisciplinary

Ultrahigh-Loading of Ir Single Atoms on NiO Matrix to Dramatically Enhance Oxygen Evolution Reaction

Qi Wang et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2020)

Article Nanoscience & Nanotechnology

Single-atom Rh/N-doped carbon electrocatalyst for formic acid oxidation

Yu Xiong et al.

NATURE NANOTECHNOLOGY (2020)

Article Chemistry, Physical

Theoretical Insights into the Thermodynamics and Kinetics of Graphene Growth on Copper Surfaces

Pai Li et al.

JOURNAL OF PHYSICAL CHEMISTRY C (2020)

Article Chemistry, Multidisciplinary

Revealing Isolated M-N3C1Active Sites for Efficient Collaborative Oxygen Reduction Catalysis

Feng Li et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2020)

Article Chemistry, Multidisciplinary

Enhancing CO2Electroreduction to Methane with a Cobalt Phthalocyanine and Zinc-Nitrogen-Carbon Tandem Catalyst

Long Lin et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2020)

Article Chemistry, Multidisciplinary

Stable and Efficient Single-Atom Zn Catalyst for CO2 Reduction to CH4

Lili Han et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2020)

Article Chemistry, Multidisciplinary

Cation-Exchange Induced Precise Regulation of Single Copper Site Triggers Room-Temperature Oxidation of Benzene

Huang Zhou et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2020)

Review Chemistry, Multidisciplinary

Single-Atom Catalysts across the Periodic Table

Selina K. Kaiser et al.

CHEMICAL REVIEWS (2020)

Article Multidisciplinary Sciences

Entropy-stabilized single-atom Pd catalysts via high-entropy fluorite oxide supports

Haidi Xu et al.

NATURE COMMUNICATIONS (2020)

Review Chemistry, Physical

Recent Advances in MOF-Derived Single Atom Catalysts for Electrochemical Applications

Zhongxin Song et al.

ADVANCED ENERGY MATERIALS (2020)

Article Multidisciplinary Sciences

Direct insights into the role of epoxy groups on cobalt sites for acidic H2O2 production

Qingran Zhang et al.

NATURE COMMUNICATIONS (2020)

Article Multidisciplinary Sciences

Multilayer stabilization for fabricating high-loading single-atom catalysts

Yazhou Zhou et al.

NATURE COMMUNICATIONS (2020)

Review Chemistry, Physical

Atomically dispersed M-N-C catalysts for the oxygen reduction reaction

Hao Xu et al.

JOURNAL OF MATERIALS CHEMISTRY A (2020)

Article Engineering, Environmental

Understanding coordination modification strategy on metal organic framework-based system for efficient water oxidation

Changqing Li et al.

CHEMICAL ENGINEERING JOURNAL (2020)

Article Chemistry, Multidisciplinary

Mechanochemical Kilogram-Scale Synthesis of Noble Metal Single-Atom Catalysts

Xiaohui He et al.

CELL REPORTS PHYSICAL SCIENCE (2020)

Review Chemistry, Physical

Densely Populated Single Atom Catalysts

Jiabin Wu et al.

SMALL METHODS (2020)

Review Chemistry, Multidisciplinary

Atomic site electrocatalysts for water splitting, oxygen reduction and selective oxidation

Di Zhao et al.

CHEMICAL SOCIETY REVIEWS (2020)

Review Chemistry, Multidisciplinary

Encapsulating Metal Nanocatalysts within Porous Organic Hosts

Xinchun Yang et al.

TRENDS IN CHEMISTRY (2020)

Article Chemistry, Multidisciplinary

Ultrahigh-Loading Zinc Single-Atom Catalyst for Highly Efficient Oxygen Reduction in Both Acidic and Alkaline Media

Jia Li et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2019)

Article Chemistry, Multidisciplinary

Binding Energy Optimization Strategy Inducing Enhanced Catalytic Performance on MIL-100(FeNi) To Catalyze Water Oxidation Directly

Changqing Li et al.

ACS SUSTAINABLE CHEMISTRY & ENGINEERING (2019)

Article Chemistry, Physical

Structural evolution of atomically dispersed Pt catalysts dictates reactivity

Leo DeRita et al.

NATURE MATERIALS (2019)

Article Chemistry, Physical

Reversible and cooperative photoactivation of single-atom Cu/TiO2 photocatalysts

Byoung-Hoon Lee et al.

NATURE MATERIALS (2019)

Article Chemistry, Multidisciplinary

Non-metal Single-Iodine-Atom Electrocatalysts for the Hydrogen Evolution Reaction

Yongqiang Zhao et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2019)

Article Chemistry, Multidisciplinary

Activity-Selectivity Trends in the Electrochemical Production of Hydrogen Peroxide over Single-Site Metal-Nitrogen-Carbon Catalysts

Yanyan Sun et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2019)

Article Multidisciplinary Sciences

Identifying the structure of Zn-N2 active sites and structural activation

Feng Li et al.

NATURE COMMUNICATIONS (2019)

Article Chemistry, Multidisciplinary

Highly Active and Stable Metal Single-Atom Catalysts Achieved by Strong Electronic Metal-Support Interactions

Junjie Li et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2019)

Article Nanoscience & Nanotechnology

High temperature shockwave stabilized single atoms

Yonggang Yao et al.

NATURE NANOTECHNOLOGY (2019)

Article Materials Science, Multidisciplinary

Boosting ionic conductivity in antiperovskite Li3OCl via defect engineering: Interstitial versus vacancy

Pai Li et al.

PHYSICAL REVIEW MATERIALS (2019)

Article Chemistry, Multidisciplinary

Tuning the Coordination Environment in Single-Atom Catalysts to Achieve Highly Efficient Oxygen Reduction Reactions

Jinqiang Zhang et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2019)

Article Chemistry, Physical

An on-demand solar hydrogen-evolution system for unassisted high-efficiency pure-water splitting

Wei Che et al.

JOURNAL OF MATERIALS CHEMISTRY A (2019)

Article Chemistry, Multidisciplinary

Microwave-Assisted Rapid Synthesis of Graphene-Supported Single Atomic Metals

Huilong Fei et al.

ADVANCED MATERIALS (2018)

Review Chemistry, Multidisciplinary

Atomically Dispersed Metal Sites in MOF-Based Materials for Electrocatalytic and Photocatalytic Energy Conversion

Zibin Liang et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2018)

Article Chemistry, Multidisciplinary

Boosting oxygen reduction catalysis with abundant copper single atom active sites

Feng Li et al.

ENERGY & ENVIRONMENTAL SCIENCE (2018)

Editorial Material Multidisciplinary Sciences

Coordination chemistry of atomically dispersed catalysts

Pengxin Liu et al.

NATIONAL SCIENCE REVIEW (2018)

Article Chemistry, Multidisciplinary

Graphene Defects Trap Atomic Ni Species for Hydrogen and Oxygen Evolution Reactions

Longzhou Zhang et al.

Review Chemistry, Multidisciplinary

Carbon-Supported Single Atom Catalysts for Electrochemical Energy Conversion and Storage

Yi Peng et al.

ADVANCED MATERIALS (2018)

Article Chemistry, Physical

Rational Design of Two-dimensional Anode Materials: B2S as a Strained Graphene

Pai Li et al.

JOURNAL OF PHYSICAL CHEMISTRY LETTERS (2018)

Article Chemistry, Multidisciplinary

Single-Site AuI Catalyst for Silane Oxidation with Water

Zheng Chen et al.

ADVANCED MATERIALS (2018)

Article Chemistry, Physical

Dominant Kinetic Pathways of Graphene Growth in Chemical Vapor Deposition: The Role of Hydrogen

Pai Li et al.

JOURNAL OF PHYSICAL CHEMISTRY C (2017)

Article Chemistry, Multidisciplinary

Asymmetric Volcano Trend in Oxygen Reduction Activity of Pt and Non-Pt Catalysts: In Situ Identification of the Site-Blocking Effect

Jingkun Li et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2017)

Article Chemistry, Multidisciplinary

Fast Photoelectron Transfer in (Cring)-C3N4 Plane Heterostructural Nanosheets for Overall Water Splitting

Wei Che et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2017)

Article Multidisciplinary Sciences

Bottom-up precise synthesis of stable platinum dimers on graphene

Huan Yan et al.

NATURE COMMUNICATIONS (2017)

Article Multidisciplinary Sciences

Identification of catalytic sites in cobalt-nitrogen-carbon materials for the oxygen reduction reaction

Andrea Zitolo et al.

NATURE COMMUNICATIONS (2017)

Article Multidisciplinary Sciences

Nanoscale tomography reveals the deactivation of automotive copper-exchanged zeolite catalysts

Joel E. Schmidt et al.

NATURE COMMUNICATIONS (2017)

Article Chemistry, Multidisciplinary

Stabilization of Single Metal Atoms on Graphitic Carbon Nitride

Zupeng Chen et al.

ADVANCED FUNCTIONAL MATERIALS (2017)

Article Chemistry, Multidisciplinary

Elongated Silicon-Carbon Bonds at Graphene Edges

Qu Chen et al.

ACS NANO (2016)

Article Chemistry, Multidisciplinary

Tackling CO Poisoning with Single-Atom Alloy Catalysts

Jilei Liu et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2016)

Article Multidisciplinary Sciences

Photochemical route for synthesizing atomically dispersed palladium catalysts

Pengxin Liu et al.

SCIENCE (2016)

Article Multidisciplinary Sciences

Quantifying the density and utilization of active sites in non-precious metal oxygen electroreduction catalysts

Nastaran Ranjbar Sahraie et al.

NATURE COMMUNICATIONS (2015)

Article Chemistry, Multidisciplinary

A Single-Site Platinum CO Oxidation Catalyst in Zeolite KLTL: Microscopic and Spectroscopic Determination of the Locations of the Platinum Atoms

Joseph D. Kistler et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2014)

Review Chemistry, Multidisciplinary

Synthesis and Stabilization of Supported Metal Catalysts by Atomic Layer Deposition

Junling Lu et al.

ACCOUNTS OF CHEMICAL RESEARCH (2013)

Article Chemistry, Multidisciplinary

Single-atom catalysis of CO oxidation using Pt1/FeOx

Botao Qiao et al.

NATURE CHEMISTRY (2011)

Article Instruments & Instrumentation

A new FEFF-based wavelet for EXAFS data analysis

Harald Funke et al.

JOURNAL OF SYNCHROTRON RADIATION (2007)

Article Materials Science, Multidisciplinary

Wavelet analysis of extended x-ray absorption fine structure data

H Funke et al.

PHYSICAL REVIEW B (2005)