Journal
ORGANIC & BIOMOLECULAR CHEMISTRY
Volume 20, Issue 19, Pages 3913-3916Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/d2ob00500j
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Funding
- National Natural Science Foundation of China [22001049]
- Guangxi Natural Science Foundation [2020GXNSFBA297003]
- Guangxi Science & Technology Base and Talent Special [AD19245095]
- PhD Scientific Research Foundation of Guilin University of Technology [GLUT2017046]
- Key Laboratory of Electrochemical and Magneto-Chemical Functional Materials [EMFM20181108]
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A palladium-catalyzed decarbonylative/decarboxylative [4 + 2] annulation of phthalic anhydrides with cyclic diaryliodonium salts to synthesize triphenylenes has been developed. The reaction shows broad substrate scope with a high yield of up to 99%, and it provides an efficient and fast way to access functionalized triphenylenes in only one hour.
A palladium-catalyzed decarbonylative/decarboxylative [4 + 2] annulation of phthalic anhydrides with cyclic diaryliodonium salts to synthesize triphenylenes has been developed. The reaction shows broad substrate scope with a high yield of up to 99%, and it provides an efficient and fast way to access functionalized triphenylenes in only one hour.
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